AIIMS 2007
- Exam
- AIIMS
- Year
- 2007
- Subject
- Chemistry
- Chapter
- Thermodynamics (C)
AIIMS 2007 · Chemistry · Thermodynamics (C)
Assertion : As a salt such as ( NaCl ) dissolves, the ( Na^ + )and...
Assertion : As a salt such as () dissolves, the ()and ()ions leaving the crystal lattice acquire far greater freedom.
Reason : In thermodyanamic terms, the formation of solution occurs with a favourable change in free energy, i.e., (H) has a high positive value and (T S) a low negative value.
Options
- AIf both assertion and reason are true and reason is the correct explanation of assertion.
- BIf both assertion and reason are true but reason is not the correct explanation of assertion.
- CIf assertion is true but reason is false.
- DIf both assertion and reason are false.
Correct answer
C. If assertion is true but reason is false.
Step-by-step solution
In thermodynamic terms, formation of solution occurs with a favourable change in free energy
(\Delta G=\Delta H-T \Delta S)
where (\Delta H) has a small positive value and (T \Delta S) a large positive value; thus (\Delta G) is negative.