NEETChemistryCarboxylic Acid Derivatives
Why do aromatic carboxylic acids not undergo Friedel-Crafts reactions?
Options
- AThe carboxyl group is activating.
- BThe carboxyl group is ortho-directing.
- CThe carboxyl group is meta-directing.
- DThe carboxyl group is a strong Lewis acid.
Correct answer
C. The carboxyl group is meta-directing.
Step-by-step solution
Aromatic carboxylic acids do not undergo Friedel-Crafts reactions because the carboxyl group is a deactivating and meta-directing group. Additionally, the Lewis acid catalyst, aluminum chloride, gets bonded to the carboxyl group.