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NEET
Exam
NEET
Subject
Chemistry
Chapter
Carboxylic Acid Derivatives

NEET · Chemistry · Carboxylic Acid Derivatives

Assertion: Carboxylic acids do not show properties of carbonyl...

Assertion: Carboxylic acids do not show properties of carbonyl group. Reason: The - (C=O\mathrm{C}=\mathrm{O}) in carboxyl group is in resonance with the -OH group.

Options

  1. ABoth assertion and reason are correct statements, and reason is the correct explanation of the assertion.
  2. BBoth assertion and reason are correct statements, but reason is not the correct explanation of the assertion.
  3. CAssertion is correct, but reason is wrong statement.
  4. DAssertion is wrong, but reason is correct statement.

Correct answer

A. Both assertion and reason are correct statements, and reason is the correct explanation of the assertion.

Step-by-step solution

- Assertion: Carboxylic acids do not show properties of carbonyl group (\rightarrow) True. Unlike aldehydes/ketones, -COOH group does not give usual carbonyl tests (like 2,4-DNP, Schiff's, Fehling's etc.) because the carbonyl carbon is less electrophilic. - Reason: The - (C=O\mathrm{C}=\mathrm{O}) in carboxyl group is in resonance with the -OH group (\rightarrow) True.
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