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NEETChemistryAmines

Match List I with List II List I (Amines) List II pKb A. Aniline I. 3 . 25 B. Ethanamine II. 3 . 00 C. N-Ethylethanamine III. 9 . 38 D. N, N-Diethylethanamine IV. 3 . 29 Choose the correct answer from the options given below:-

Options

  1. AA-I, B-IV, C-II, D-III
  2. BA-III, B-II, C-I, D-IV
  3. CA-III, B-II, C-IV, D-I
  4. DA-III, B-IV, C-II, D-I

Correct answer

D. A-III, B-IV, C-II, D-I

Step-by-step solution

Among given aliphatic amines, 2° amine is most basic, followed by 3° amine and 1° amine. Therefore, the correct basic strength (K b ) order of the given amines is (C) > (D) > (B) > (A) The pK b order of the given amines will be just the opposite of their basic strength order. The order is (A) > (B) > (D) > (C) So the correct answer is A-III, B-IV, C-II, D-I

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