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NEET Amines PYQs with Solutions

564 previous year questions from Amines (NEET UG Chemistry) with answers and solutions. Numbered list, year tags, and one-tap solutions — built for serious JEE / NEET practice.

564 questionsChemistry2002–2026Answers + solutions

About Amines PYQs

Amines has 564 previous year questions in the Quantrex Academy NEET UG Chemistry bank. The 220 questions in this list come from NEET (181), MHT CET Medical (22) and JIPMER (17), spanning 2002 to 2026. Each question opens on its own page with the options, the correct answer and the worked solution where available.

Questions by year (this list)

  • 2026: 25
  • 2025: 2
  • 2024: 4
  • 2023: 2
  • 2022: 3
  • 2021: 1
  • 2020: 2
  • 2019: 1
  • 2017: 6
  • 2016: 6
  • 2015: 4
  • 2014: 1

Amines questions with solutions

1

IN a chemical reaction Aniline is treated with NaNO_2 and HCl to form a compound X. When X is further hydrolyzed by supplying heat it forms compound Z. Identify Z in this reaction.

MHT CET Medical 2026 Solution
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2

Which of the following compounds is converted to sulfanilic acid by sulfonation?

MHT CET Medical 2026 Solution
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3

Identify the product obtained when nitro alkanes are treated with Sn / HCl.

MHT CET Medical 2026 Solution
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4

Identify the activity of ammonia due to the presence of lone pair of electrons in it, from following.

MHT CET Medical 2026 Solution
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5

Which of the following is least alkaline ?

MHT CET Medical 2026 Solution
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6

What type of compound the aniline is?

MHT CET Medical 2026 Solution
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7

What type of amine is tert-Butyl amine?

MHT CET Medical 2026 Solution
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8

Which is the correct decreasing order of boiling point for following amines? Tertiary amine (I), Secondary amine (II), Primary amine (III)

MHT CET Medical 2026 Solution
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9

The chemical formula of Hinsberg reagent is:

MHT CET Medical 2026 Solution
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10

Identify product 'B' in the following sequence of reactions. Aniline NaNO_2+HCl,\ 273\ K A H_2O,\ Δ B+N_2

MHT CET Medical 2026 Solution
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11

Which of the following amines has imino functional group?

MHT CET Medical 2026 Solution
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12

Which of the following methods is the most convenient method to prepare an amine containing one carbon atom less than the parent compound?

MHT CET Medical 2026 Solution
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13

Which of the following statments is NOT correct for benzene sulfonyl chloride?

MHT CET Medical 2026 Solution
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14

What is the number of -NH_2 groups present in hexamethylenediamine?

MHT CET Medical 2026 Solution
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15

Acetonitrile on reduction with sodium in ethanol gives A, which reacts with NaNO_2 and dil. HCl to form B. Identify product B.

MHT CET Medical 2026 Solution
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16

Identify the weakest base almong the following.

MHT CET Medical 2026 Solution
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17

Which one of the following compounds has the highest boiling point?

MHT CET Medical 2026 Solution
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18

What type of amine is (C_2H_5)_2NH ?

MHT CET Medical 2026 Solution
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19

Aniline undergoes diazotization with NaNO_2 /HCl to give compound A. Compound A reacts with fluoroboric acid to give compound B. When B is heated with aq. NaNO_2 in the presence

MHT CET Medical 2026 Solution
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20

Identify the reaction that converts CH_3CN to CH_3-CH_2-NH_2 .

MHT CET Medical 2026 Solution
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21

Identify the product when ethyl amine reacts with nitrous acid in cold.

MHT CET Medical 2026 Solution
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22

Which of the following is least basic than aniline?

MHT CET Medical 2026 Solution
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23

Select the reagents that reduce nitriles to primary amines : A. (i) LiAlH_4 ; (ii) H_2O B. Sn + HCl C. H_2/Ni D. Na(Hg)/C_2H_5OH E. Br_2/aq. NaOH Choose the correct answer from

NEET 2026 Solution
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24

Identify the reactions which give aniline as the major product. Choose the correct answer from the options given below.

NEET 2026 Solution
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25

The major product Z formed in the following sequence of reactions is : C_2H_6 [UV light] Cl_2 X NH_3 Y [(monochlorinated product)] (i) NaNO_2/HCl\ \ (ii) H_2O Z

NEET 2026 Solution
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26

The correct order of decreasing basic strength of the given amines is :

NEET 2025 Solution
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27

Given below are two statements : Statement I : Benzenediazonium salt is prepared by the reaction of aniline with nitrous acid at 273-278 K. It decomposes easily in the dry state.

NEET 2025 Solution
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28

The compound that does not undergo Friedel-Crafts alkylation reaction but gives a positive carbylamine test is :

NEET 2024 Solution
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29

Identify the major product C formed in the following reaction sequence:

NEET 2024 Solution
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30

Given below are two statements: Statement I : Aniline does not undergo Friedel-Crafts alkylation reaction. Statement II : Aniline cannot be prepared through Gabriel synthesis. In

NEET 2024 Solution
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31

Select the incorrect reaction among the following:

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32

Which amongst the following compounds/species is least basic?

NEET 2023 Solution
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33

Which of the following reactions will NOT give primary amine as the product?

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34

The product formed from the following reaction sequence is

NEET 2022 Solution
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35

Match List-I with List-II : List-I List-II (Reaction) (Product formed) (a) Gabriel synthesis (i) Benzaldehyde (b) Kolbe synthesis (ii) Ethers (c) Williamson synthesis (iii)

NEET 2022 Solution
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36

Given below are two statements: Statement I: Primary aliphatic amines react with HNO _ 2 to give unstable diazonium salts. Statement II : Primary aromatic amines react with HNO _

NEET 2022 Solution
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37

Identify the compound that will react with Hinsberg's reagent to give a solid which dissolves in alkali.

NEET 2021 Solution
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38

Which of the following amine will give the carbylamine test?

NEET 2020 Solution
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39

Reaction of propanamide with ethanolic sodium hydroxide and bromine will give

NEET 2020 Solution
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40

The amine that reacts will Hinsberg's reagent to give an alkali insoluble product is

NEET 2019 Solution
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41

In the reaction, In the given reaction (B) is

JIPMER 2017 Solution
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42

Consider the following reaction, X Bromination Y [+HCl] NaNO_2 Z [C_2 H_5 OH] Boiling Tribromo-benzene. X is

JIPMER 2017 Solution
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43

The main product formed in the following reaction is (1 equivalent) Product.

JIPMER 2017 Solution
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44

The correct order of basic strength of the following are

JIPMER 2017 Solution
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45

Which of the following reaction is appropriate for converting acetamide to methanamine?

NEET 2017 Solution
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46

The correct increasing order of the basic strength for the following compounds is:

NEET 2017 Solution
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47

C_6 H_5-NHOH+C_6 H_5-NO NaOH (X),(X) formed in the above reaction is

JIPMER 2016 Solution
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48

Consider the following reaction sequence Choose the correct option regarding the different products obtained in the above reaction sequence.

JIPMER 2016 Solution
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49

C_3 H_9 ~N reacts with Hinsberg reagent and the product is insoluble in alkali but soluble in ether. This nitrogen containing compound is

JIPMER 2016 Solution
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50

Which of the following is an example of carbylamine reaction?

JIPMER 2016 Solution
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51

A given nitrogen-containing aromatic compound A reacts with Sn / HCl , followed by HN O _ 2 to give an unstable compound B . B on treatment with phenol, forms a beautiful coloured

NEET 2016 Solution
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52

Which one of the following nitro-compounds does not react with nitrous acid?

NEET 2016 Solution
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53

The correct order of basic strength of the following are

JIPMER 2015 Solution
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54

The following reaction Is known by the name:

NEET 2015 Solution
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55

Method by which Aniline cannot be prepared is:

NEET 2015 Solution
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56

The electrolytic reduction of nitrobenzene in strongly acidic medium produces:

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57

In the following reaction, the product ( A )

NEET 2014 Solution
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58

Some reaction of amines are given. Which one is not correct?

NEET 2013 Solution
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59

Consider the following reaction, C_6 H_5 NO_2 Sn / HCl X C_6 H_5 COCl Y+HCl What is Y ?

JIPMER 2012 Solution
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60

Which of the following is most basic in nature?

JIPMER 2012 Solution
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61

An organic compound (C_3 H_9 ~N)(A) , when treated with nitrous acid, gave an alcohol and N_2 gas was evolved. (A) on warming with CHCl_3 and caustic potash gave (C) which on

NEET 2012 Solution
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62

Amine that cannot be prepared by Gabriel phthalimide synthesis is

JIPMER 2011 Solution
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63

What is the product obtained in the following reaction?

NEET 2011 Solution
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64

An organic compound ' A ' on treatment with NH_3 gives ' B ' which on heating gives ' C ', ' C ' when treated with Br_2 in the presence of KOH produces ethylamine. Compound ' A '

NEET 2011 Solution
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65

Which of the organic compounds will give red colour in Lassaigne test?

JIPMER 2010 Solution
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66

Gabriel phthalimide reaction is used for the preparation of

JIPMER 2010 Solution
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67

Acetamide is treated with the following reagents separately. Which one of these would yield methyl amine ?

NEET 2010 Solution
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68

Aniline in a set of the following reactions yielded a coloured product ' Y . The structure of ' Y ' would be

NEET 2010 Solution
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69

Match the compounds given in List I with their characteristic reactions given in List II. Select the correct option.

NEET 2010 Solution
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70

During, acetylation of amines, what is replaced by acetyl group?

JIPMER 2009 Solution
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71

Predict the product,

NEET 2009 Solution
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72

Structures of some common polymers are given which one is not correctly presented?

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73

In a reaction of ani line a coloured product C was obtained. The structure of C would be

NEET 2008 Solution
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74

How many moles of lead (II) chloride will be formed from a reaction between 6.5 ~g of PbO and 3.2 ~g of HCl ?

NEET 2008 Solution
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75

Aniline in a set of reactions yielded a product D . The structure of the product D would be

JIPMER 2007 Solution
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76

Which one of the following on reduction with lithium aluminium hydride yields a secondary amine?

NEET 2007 Solution
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77

R-NH-COH [ Pyridine ] POCl_3 product In the given reaction, what will be the product?

JIPMER 2006 Solution
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78

In a set of reactions propionic acid yielded a compound 'd'. \(CH_2 CH_2 COOH SOCl_2 ^ b^ NH_3 ^ c^ [Br_2] KOH ^ d^ \) The structure of 'd' would be:

NEET 2006 Solution
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79

Which of the following is more basic than aniline?

NEET 2006 Solution
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80

Electrolytic reduction of nitrobenzene in weakly acidic medium gives:

NEET 2005 Solution
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81

Aniline in a set of reactions yielded a product ' d ': The structure of the product ' d ' would be

NEET 2005 Solution
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82

The major organic product formed from the following reaction:

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83

Aniline when diazotised in cold and then treated with dimethyl aniline gives a coloured product. Its structure would be:

NEET 2004 Solution
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84

The final product ' c ', obtained in this reaction would be

NEET 2003 Solution
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85

Z in the above reaction sequence is:

NEET 2002 Solution
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86

Why can't aromatic primary amines be prepared by Gabriel synthesis?

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87

Why is p-toluenesulfonyl chloride often used instead of benzenesulfonyl chloride?

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88

In the reaction with primary amine, what type of sulphonamide is formed?

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89

Which of the following metals is NOT commonly used as a catalyst for the reduction of nitro compounds to amines?

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90

What type of reaction is involved when phthalimide reacts with an alkyl halide in the Gabriel synthesis?

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91

What type of compounds are prepared by the reduction of nitriles using LiAlH4 or catalytic hydrogenation?

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92

Why does aniline have a higher pKb value compared to ammonia?

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93

What is the reagent used in the carbylamine test for primary amines?

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94

Which of the following is true regarding the reduction of nitriles to primary amines?

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95

What is the role of sodium hydroxide (NaOH) in the Hoffmann bromamide degradation reaction?

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96

In a nucleophilic substitution reaction, what is the product when a nitroalkane reacts with a nucleophile?

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97

What kind of group migration occurs in the Hoffmann bromamide degradation?

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98

Which of the following reagents is commonly used for the substitution of a halogen atom with an alkyl group in a haloalkane?

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99

In the Gabriel synthesis, what reaction occurs when the potassium salt of phthalimide reacts with an alkyl halide?

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100

How are amine salts separated from non-basic organic compounds?

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101

What is the product obtained when nitrile is reduced with lithium aluminum hydride (LiAlH 4 )?

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102

What is the change in the number of carbon atoms when an amide is subjected to the Hoffmann bromamide degradation reaction?

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103

How does the proton acceptability of aniline compare to that of ammonia?

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104

Why is the reduction of nitro compounds with iron scrap and hydrochloric acid preferred?

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105

Which of the following is an example of an ambident nucleophile?

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106

What is a common use of the reaction of primary aliphatic amines with nitrous acid?

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107

What is the characteristic odour of the products formed in the Carbylamine reaction?

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108

What is the order of reactivity of halides with amines, from most reactive to least reactive?

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109

Which functional group is retained in the primary amine formed by the Hoffmann bromamide degradation?

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110

Which of the following amines will have the highest basic strength in aqueous solution?

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111

What is the product of the reaction of amines with benzoyl chloride (C 6 H 5 COCl)?

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112

What is the starting material in the Gabriel synthesis for the preparation of primary amines?

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113

What is the key transformation that occurs in the Hoffmann bromamide degradation reaction?

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114

How can the free amine be obtained from the quaternary ammonium salt formed during the ammonolysis reaction?

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115

What property of amines does the reaction with benzenesulfonyl chloride help distinguish?

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116

Nucleophilic substitution reactions often involve the replacement of:

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117

Which effect dominates the order of basicity when comparing methyl-substituted and ethyl-substituted amines in aqueous solution?

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118

During the reduction of nitro compounds with iron scrap and hydrochloric acid, what role does FeCl 2 play?

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119

Which factor primarily determines the basicity of amines?

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120

What is the primary product obtained when aliphatic or aromatic primary and secondary amines react with acid chlorides, anhydrides, or esters?

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