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NEETChemistryAmines

Account for the following statement- Although the amino group is o– and p– directing in aromatic electrophilic substitution reactions, aniline on nitration gives a substantial amount of m-nitroaniline.

Options

  1. AAniline on nitration gives a substantial amount of m-nitroaniline because nitration is carried out in acidic m
  2. BAniline's amino group undergoes a tautomeric shift to a meta-directing form during nitration.
  3. CAniline has steric hindrance that favors substitution at the meta position.
  4. DAniline forms a highly reactive complex with the nitrating agent, leading to meta substitution.

Correct answer

A. Aniline on nitration gives a substantial amount of m-nitroaniline because nitration is carried out in acidic m

Step-by-step solution

Correct Option is : (A) Aniline on nitration gives a substantial amount of m-nitroaniline because nitration is carried out in acidic medium , in which aniline gets protonated to form anilinium ion which is a meta directing species.

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