NEETChemistryAmines
Account for the following statement- Although the amino group is o– and p– directing in aromatic electrophilic substitution reactions, aniline on nitration gives a substantial amount of m-nitroaniline.
Options
- AAniline on nitration gives a substantial amount of m-nitroaniline because nitration is carried out in acidic m
- BAniline's amino group undergoes a tautomeric shift to a meta-directing form during nitration.
- CAniline has steric hindrance that favors substitution at the meta position.
- DAniline forms a highly reactive complex with the nitrating agent, leading to meta substitution.
Correct answer
A. Aniline on nitration gives a substantial amount of m-nitroaniline because nitration is carried out in acidic m
Step-by-step solution
Correct Option is : (A) Aniline on nitration gives a substantial amount of m-nitroaniline because nitration is carried out in acidic medium , in which aniline gets protonated to form anilinium ion which is a meta directing species.