Quantrex Quantrex AcademyJEE · NEET · NDA PYQs with solutions Open app
NEETChemistryAmines

Identify the major product C formed in the following sequence of reactions: Benzamide Br ₂/ NaOH A [ 273-278 K ] NaNO ₂/ HCl B H ₂ O, warm C

Options

  1. ABenzene diazonium chloride
  2. BBromobenzene
  3. CPhenol
  4. DBenzyl alcohol

Correct answer

C. Phenol

Step-by-step solution

Benzamide undergoes Hoffmann bromamide degradation with Br ₂ and NaOH to form aniline ( A ). C ₆ H ₅ CONH ₂ Br ₂/ NaOH C ₆ H ₅ NH ₂ (A) Aniline reacts with nitrous acid ( NaNO ₂ and HCl ) at 273-278 K to undergo diazotization, forming benzene diazonium chloride ( B ). C ₆ H ₅ NH ₂ [ 273-278 K ] NaNO ₂/ HCl C ₆ H ₅ N ₂⁺ Cl ⁻ (B) Warming the stable aromatic diazonium salt with water hydrolyses it to yield phenol ( C ). C ₆ H ₅ N ₂⁺ Cl ⁻ H ₂ O, warm C ₆ H ₅ OH (C) + N ₂ + HCl Thus, the major product C is phenol. Benze

Practice Amines on Quantrex Academy →

More from Amines

IN a chemical reaction Aniline is treated with NaNO ₂ and HCl to form a compound X. When X is further hydrolyzed by supplying heat it forms compound Z. Identify Z in this reaction. 2026Which of the following compounds is converted to sulfanilic acid by sulfonation? 2026Identify the product obtained when nitro alkanes are treated with Sn / HCl. 2026Identify the activity of ammonia due to the presence of lone pair of electrons in it, from following. 2026Which of the following is least alkaline ? 2026What type of compound the aniline is? 2026What type of amine is tert-Butyl amine? 2026Which is the correct decreasing order of boiling point for following amines? Tertiary amine (I), Secondary amine (II), Primary amine (III) 2026 Full Amines list All NEET PYQs