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NEET2015ChemistryAminesActual

The reaction of a primary amine with chloroform and ethanolic solution of KOH is called

Options

  1. AHofmann's reaction
  2. Bcoupling reaction
  3. Ccarbylamine reaction
  4. DCurtius reaction.

Correct answer

C. carbylamine reaction

Step-by-step solution

In carbylamine reaction, aliphatic and aromatic primary amines on heating with chloroform and ethanolic KOH , form isocyanides or carbylamines which are foul smelling substances. aligned & R- NH ₂+ CHCl ₃+3 KOH _ ( alc. ) & R- NC +3 KCl +3 H ₂ O & aligned

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