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BITSAT2016Chemistryd and f Block ElementsActual

Knowing that the chemistry of lanthanoids(Ln) is dominated by its +3 oxidation state, which of the following statements is incorrect?

Options

  1. AThe ionic size of Ln (III) decrease in general with increasing atomic number
  2. BLn (III) compounds are generally colourless.
  3. CLn (III) hydroxide are mainly basic in character.
  4. DBecause of the large size of the Ln (III) ions the bonding in its compounds is predominantly ionic in characte

Correct answer

B. Ln (III) compounds are generally colourless.

Step-by-step solution

Most of the Ln ³⁺ compounds except La ³⁺ and Lu ³⁺ are coloured due to the presence of f -electrons.

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