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BITSAT 2010
Exam
BITSAT
Year
2010
Subject
Chemistry
Chapter
d and f Block Elements

BITSAT 2010 · Chemistry · d and f Block Elements

Which one of the following statements is correct?

Which one of the following statements is correct?

Options

  1. AFrom a mixed precipitate of AgCl\mathrm{AgCl} and AgI\mathrm{AgI}, ammonia solution dissolves only AgCl\mathrm{AgCl}.
  2. BFerric ions give a deep green precipitate on adding potassium ferrocyanide solution.
  3. COn boiling a solution having K+,Ca2+and\mathrm{K}^{+}, \mathrm{Ca}^{2+} and\mathrm{HCO}_{3}^{-}ionswegetaprecipitateofions we get a precipitate of\mathrm{K}_{2} \mathrm{Ca}(CO3)2\left(\mathrm{CO}_{3}\right)_{2}
  4. DManganese salts give a violet borax bead test in the reducing flame.

Correct answer

A. From a mixed precipitate of AgCl\mathrm{AgCl} and AgI\mathrm{AgI}, ammonia solution dissolves only AgCl\mathrm{AgCl}.

Step-by-step solution

Ammonia can dissolve ppt. of AgCl only due to formation of complex as given below: AgCl+2NH3→[Ag(NH3)2]Cl\mathrm{AgCl}+2 \mathrm{NH}_{3} \rightarrow\left[\mathrm{Ag}\left(\mathrm{NH}_{3}\right)_{2}\right] \mathrm{Cl}
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