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BITSAT 2023Paper 2
Exam
BITSAT
Year
2023
Paper
Paper 2
Subject
Chemistry
Chapter
Electrochemistry

BITSAT 2023 · Paper 2 · Chemistry · Electrochemistry

Given that E_ O_2 / H_2 O^ ^ =+1.23 V ; aligned & E_ S_2 O_8^ 2- /...

Given that E_{\mathrm{O}_2 / \mathrm{H}_2 \mathrm{O}^{{}^{\circ}}=+1.23 \mathrm{ V};
\begin{aligned} \\ & E_{\mathrm{S}_2 \mathrm{O}_8^{2-} / \mathrm{SO}_4^{2-}}^{{}^{\circ}}=2.05 \mathrm{ V} ; E_{\mathrm{Br}_2 / \mathrm{Br}^{-}}^{{}^{\circ}}=+1.09 \mathrm{ V} \\ \\ & E_{\mathrm{Au}^{3+} / \mathrm{Au}^{{}^{\circ}}=+1.4 \mathrm{ V} \\ \end{aligned}
The strongest oxidising agent is :

Options

  1. AAu3+\mathrm{Au}^{3+}
  2. BO2\mathrm{O}_2
  3. CS2O82−\mathrm{S}_2 \mathrm{O}_8^{2-}
  4. DBr2\mathrm{Br}_2

Correct answer

C. S2O82−\mathrm{S}_2 \mathrm{O}_8^{2-}

Step-by-step solution

Reduction potential is maximum for S2O82−\mathrm{S}_2 \mathrm{O}_8{ }^{2-} therefore, it is the strongest oxidising agent amongst the given species.
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