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BITSAT 2023Paper 1
Exam
BITSAT
Year
2023
Paper
Paper 1
Subject
Chemistry
Chapter
General Principles and Processes of Isolation of Metals

BITSAT 2023 · Paper 1 · Chemistry · General Principles and Processes of Isolation of Metals

The reaction that does NOT take place in a blast furnace between...

The reaction that does NOT take place in a blast furnace between 900K900 \mathrm{ K} to 1500K1500 \mathrm{ K} temperature range during extraction of iron is :

Options

  1. AFe2O3+CO→2FeO+CO2\mathrm{Fe}_2 \mathrm{O}_3+\mathrm{CO} \rightarrow 2 \mathrm{FeO}+\mathrm{CO}_2
  2. BFeO+CO→Fe+CO2\mathrm{FeO}+\mathrm{CO} \rightarrow \mathrm{Fe}+\mathrm{CO}_2
  3. CC+CO2→2CO\mathrm{C}+\mathrm{CO}_2 \rightarrow 2 \mathrm{CO}
  4. DCaO+SiO2→CaSiO3\mathrm{CaO}+\mathrm{SiO}_2 \rightarrow \mathrm{CaSiO}_3

Correct answer

A. Fe2O3+CO→2FeO+CO2\mathrm{Fe}_2 \mathrm{O}_3+\mathrm{CO} \rightarrow 2 \mathrm{FeO}+\mathrm{CO}_2

Step-by-step solution

At 900−1500K900-1500 \mathrm{ K} (higher temperature range in the blast furnace)
Reaction which take place are:
C+CO2⟶2CO\mathrm{C}+\mathrm{CO}_2 \longrightarrow 2 \mathrm{CO}
FeO+CO⟶Fe+CO2\mathrm{FeO}+\mathrm{CO} \longrightarrow \mathrm{Fe}+\mathrm{CO}_2
CaO+SiO2⟶CaSiO3\mathrm{CaO}+\mathrm{SiO}_2 \longrightarrow \mathrm{CaSiO}_3 (Slag formation)
Fe2O3+CO⟶2FeO+CO2\mathrm{Fe}_2 \mathrm{O}_3+\mathrm{CO} \longrightarrow 2 \mathrm{FeO}+\mathrm{CO}_2 at 500−800K500-800 \mathrm{ K}
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