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BITSAT2020ChemistryGeneral Principles and Processes of Isolation of MetalsActual

_ f G ⁻ vs T plot in the Ellingham diagram slopes downward for the reaction

Options

  1. AMg + 1 2 O ₂ MgO
  2. B2 Ag + 1 2 O ₂ Ag ₂ O
  3. CC + 1 2 O ₂ CO
  4. DCO + 1 2 O ₂ CO ₂

Correct answer

C. C + 1 2 O ₂ CO

Step-by-step solution

C ( s )+ 1 2 O ₂( ~g ) CO ( g ) ; S increases. Hence, as the temperature increases, T S increases and hence G ( H - T S ) decreases. In other words, the slope of the curve for formation of CO decreases. However, for all other oxides, it increases.

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