BITSAT 2019
- Exam
- BITSAT
- Year
- 2019
- Subject
- Chemistry
- Chapter
- p Block Elements (Group 13 & 14)
BITSAT 2019 · Chemistry · p Block Elements (Group 13 & 14)
The order of acidic strength of boron trihalides
The order of acidic strength of boron trihalides

Options
- A
- B
- C
- D
Correct answer
A.
Step-by-step solution
The strength of acidic character of boron trihalides depends upon back bonding.
In boron trihalides, -back bonding occurs due to empty orbital of boron and filled orbitals of halogens.

The back bonding is shown maximum by , as the size of and are small and comparatively same. Due to this effect tendency of accepting lone-pair of electrons of boron decreases as size of halogen increases. The order of size of halogens are . Thus, acidic nature is in order