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BITSAT 2019
Exam
BITSAT
Year
2019
Subject
Chemistry
Chapter
p Block Elements (Group 13 & 14)

BITSAT 2019 · Chemistry · p Block Elements (Group 13 & 14)

The order of acidic strength of boron trihalides

The order of acidic strength of boron trihalidesThe order of acidic strength of boron trihalides

Options

  1. ABF3<BCl3<BBr3<BI3{BF}_{3} < {BCl}_{3} < {BBr}_{3} < {BI}_{3}
  2. BBI3<BBr3<BCl3<BF3{BI}_{3} < {BBr}_{3} < {BCl}_{3} < {BF}_{3}
  3. CBCl3<BBr3<BI3<BF3{BCl}_{3} < {BBr}_{3} < {BI}_{3} < {BF}_{3}
  4. DBBr3<BCl3<BF3<BI3{BBr}_{3} < {BCl}_{3} < {BF}_{3} < {BI}_{3}

Correct answer

A. BF3<BCl3<BBr3<BI3{BF}_{3} < {BCl}_{3} < {BBr}_{3} < {BI}_{3}

Step-by-step solution

The strength of acidic character of boron trihalides depends upon pπ−pπp \pi - p \pi back bonding.

In boron trihalides, pπ−pπp \pi - p \pi -back bonding occurs due to empty orbital of boron and filled orbitals of halogens.

The order of acidic strength of boron trihalides

The pπ−pπp \pi - p \pi back bonding is shown maximum by BF3{BF}_{3}, as the size of BB and FF are small and comparatively same. Due to this effect tendency of accepting lone-pair of electrons of boron decreases as size of halogen increases. The order of size of halogens are F<Cl<Br<IF < Cl < Br < I. Thus, acidic nature is in order

BF3<BCl3<BBr3<BI3{BF}_{3} < {BCl}_{3} < {BBr}_{3} < {BI}_{3}

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