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BITSAT 2018
Exam
BITSAT
Year
2018
Subject
Chemistry
Chapter
p Block Elements (Group 13 & 14)

BITSAT 2018 · Chemistry · p Block Elements (Group 13 & 14)

A mixture of Boron trichloride and hydrogen is subjected to silent...

A mixture of Boron trichloride and hydrogen is subjected to silent electric discharge to form xx and HClHCl. xx is mixed with NH3{NH}_{3} and heated to 2000C{200}^{0}C to form yy. The formula of yy is

Options

  1. AB2O3{B}_{2}{O}_{3}
  2. BB3N3H6{B}_{3}{N}_{3}{H}_{6}
  3. CH3BO3{H}_{3}{BO}_{3}
  4. DB2H6{B}_{2}{H}_{6}

Correct answer

B. B3N3H6{B}_{3}{N}_{3}{H}_{6}

Step-by-step solution

When a mixture of BCl3{BCl}_{3} and H2{H}_{2} is subjected to silent electric discharge, diborane and HClHCl are formed. Diborane reacts with NH3{NH}_{3} at 200°C200 ° C to give Borazine (inorganic benzene).

2BCl3+6H2→dischargeElectricB2H6x+6HCl2{BCl}_{3} + 6{H}_{2}\mathop{→}_{discharge}^{Electric}\mathop{{B}_{2}{H}_{6}}_{x} + 6HCl

3B2H61+6NH32⟶200°C2B3N3H6Borazine(y)+12H2\mathop{3{B}_{2}{H}_{6}}_{1} + \mathop{6{NH}_{3}}_{2}\overset{200 ° C}{⟶}\mathop{2{B}_{3}{N}_{3}{H}_{6}}_{Borazine ( y )} + 12{H}_{2}

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