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BITSAT 2024
Exam
BITSAT
Year
2024
Subject
Chemistry
Chapter
Redox Reactions

BITSAT 2024 · Chemistry · Redox Reactions

What is the stoichiometric coefficient of SO_2 in the following...

What is the stoichiometric coefficient of SO2\mathrm{SO}_2 in the following balance reaction? MnO4−(aq)+SO2(g)⟶Mn2+(aq)+HSO4−(aq)\mathrm{MnO}_4^{-}(a q)+\mathrm{SO}_2(g) \longrightarrow \mathrm{Mn}^{2+}(a q)+\mathrm{HSO}_4^{-}(a q) (in acidic solution)

Options

  1. A5
  2. B4
  3. C3
  4. D2

Correct answer

A. 5

Step-by-step solution

Oxidation half reaction: SO2(g)+2H2O(l)⟶HSO4−(aq)+3H+(aq)+2e−...(i)\mathrm{SO}_2(\mathrm{ g})+2 \mathrm{H}_2 \mathrm{O}(l) \longrightarrow \mathrm{HSO}_4^{-}(a q)+3 \mathrm{H}^{+}(a q)+2 e^{-}...(i) Reduction half reaction: MnO4−(aq)+8H++5e−⟶Mn2+(aq)+4H2O(l)...(ii)\mathrm{MnO}_4^{-}(a q)+8 \mathrm{H}^{+}+5 e^{-} \longrightarrow \mathrm{Mn}^{2+}(a q)+4 \mathrm{H}_2 \mathrm{O}(l)...(ii) Multiply eq. (i) by 5 and (ii) by 2 and then add 2MnO4−(aq)+5SO2(g)+2H2O(l)+H+(aq)⟶2Mn+(aq)+5HSO4−(aq)\begin{aligned} 2 \mathrm{MnO}_4^{-}(a q)+5 \mathrm{SO}_2(g) & +2 \mathrm{H}_2 \mathrm{O}(l)+\mathrm{H}^{+}(a q) \\ & \longrightarrow 2 \mathrm{Mn}^{+}(a q)+5 \mathrm{HSO}_4^{-}(a q) \end{aligned} Thus, the stoichiometric coefficient of SO2\mathrm{SO}_2 in the above balance equation is 5.
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