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BITSAT 2019
Exam
BITSAT
Year
2019
Subject
Chemistry
Chapter
Redox Reactions

BITSAT 2019 · Chemistry · Redox Reactions

0. 45g acid of molecular mass 90 was neutralise by 20ml of 0. 5NKOH...

0.45g0. 45g acid of molecular mass 9090 was neutralise by 20ml20ml of 0.5NKOH0. 5NKOH. The basicity of the acid is

Options

  1. A22
  2. B44
  3. C11
  4. D33

Correct answer

A. 22

Step-by-step solution

Given that& 0.45g0 . 45g of the acid of molecular mass& 9090 was neutralized by& 20ml20ml of& 0.50 . 5\left(N\right)causticpotash.</p><p>Weknowthat,</p><p>Normality(N)=Weightofthebase×1000Eq.weight×volumecaustic potash.</p><p>We know that,</p><p>Normality\left(N\right) = \dfrac{Weightofthebase \times 1000}{Eq . weight \times volume}</p><p></p><p>∵Gramequivalentsofanacid</p><p>GramequivalentsofGram equivalents of an acid</p><p>Gram equivalents ofKOHi.e.i.e.0.45E=20×0.51000\dfrac{0 . 45}{E} = \dfrac{20 \times 0 . 5}{1000}

where, E=E = Equivalent mass E=0.45×100020×0.5=45E = \dfrac{0 . 45 \times 1000}{20 \times 0 . 5} =45

Thus, basicity =9045=2[∵Basicity=MolecularmassEquivalentmass]= \dfrac{90}{45} =2 \left[∵ Basicity = \dfrac{Molecular mass}{Equivalent mass}\right]

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