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BITSAT 2011
Exam
BITSAT
Year
2011
Subject
Chemistry
Chapter
Solutions

BITSAT 2011 · Chemistry · Solutions

1.00 ~g of a non-electrolyte solute (molar mass .250 ~g ~mol^ -1 )...

1.00 g1.00 \mathrm{~g} of a non-electrolyte solute (molar mass 250 g mol−1)\left.250 \mathrm{~g} \mathrm{~mol}^{-1}\right) was dissolved in 51.2 g51.2 \mathrm{~g} of benzene. If the freezing point depression constant, Kf\mathrm{K}_{\mathrm{f}} of benzene is 5.12 K kg mol−15.12 \mathrm{~K} \mathrm{~kg} \mathrm{~mol}^{-1}, the freezing point of benzene will be lowered by

Options

  1. A0.3K0.3 \mathrm{ K}
  2. B0.5K0.5 \mathrm{ K}
  3. C0.4K0.4 \mathrm{ K}
  4. D0.2

Correct answer

C. 0.4K0.4 \mathrm{ K}

Step-by-step solution

ΔTf=Kfm=5.12×1250×100051.2=0.4K\Delta \mathrm{T}_{\mathrm{f}}=\mathrm{K}_{\mathrm{f}} \mathrm{m}=5.12 \times \frac{1}{250} \times \frac{1000}{51.2}=0.4 \mathrm{ K}
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