Which one of the following statements is false?

Options

AThe correct order of osmotic pressure for 0.01 M aqueous solution of each compound is $\mathrm{BaCl}_{2} > \mathrm{KCl} > \mathrm{CH}_{3} \mathrm{COOH} >$ sucrose.
BThe osmotic pressure $(\pi)$ of a solution is given by the equation $\pi=\mathrm{MRT}$ , where $\mathrm{M}$ is the molarity of the solution.
CRaoult's law states that the vapour pressure of a component over a solution is proportional to its mole fraction.
DTwo sucrose solutions of same molality prepared in different solvents will have the same freezing point depression.

D. Two sucrose solutions of same molality prepared in different solvents will have the same freezing point depression.

\Delta \mathrm{T}_{\mathrm{f}}=\mathrm{K}_{\mathrm{f}} \times \mathrm{m} \times \mathrm{i}

. Since

\mathrm{K}_{\mathrm{f}}

has different values for different solvents, hence even if the

\mathrm{m}

is the same

\Delta \mathrm{T}_{\mathrm{f}}

will be different.