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BITSAT 2019
Exam
BITSAT
Year
2019
Subject
Chemistry
Chapter
Structure of Atom

BITSAT 2019 · Chemistry · Structure of Atom

The wavelength corresponding to maximum energy for hydrogen is 91....

The wavelength corresponding to maximum energy for hydrogen is 91.2nm91. 2nm. The corresponding wavelength for He+{He}^{+} ion is

Options

  1. A2.28nm2. 28nm
  2. B22.8nm22. 8nm
  3. C182.4nm182. 4nm
  4. D364.8nm364. 8nm

Correct answer

B. 22.8nm22. 8nm

Step-by-step solution

Accordinq to Rydberg's equation

v¯=1λ=RZ2[1nL2−1nH2]\overset{¯}{v} = \dfrac{1}{\lambda} = {RZ}^{2}\left[1{n}_{L}^{2} - 1{n}_{H}^{2}\right]

where,

v¯=\overset{¯}{v} = wave number

λ=\lambda = wavelength

R=R = Rydberg constant \left(= 109677{cm}^{- 1}\right)</p><p></p><p>Z =atomicnumber</p><p>atomic number</p><p>{n}_{L} =lowerenergystate</p><p>lower energy state</p><p>{n}_{H} =higherenergystate.</p><p>i.e.higher energy state.</p><p>i.e.\dfrac{1}{\lambda} ∝ {Z}^{2}</p><p>Thus,</p><p>Thus,\dfrac{\lambda\left({He}^{+}\right)}{\lambda\left(H\right)} = \dfrac{{Z}^{2}\left(H\right)}{{Z}^{2}\left({He}^{+}\right)}</p><p>Tofind</p><p>To find\lambda\left({He}^{+}\right) = ?</p><p>Given,</p><p>Given,\lambda\left(H\right) = 91 . 2nm</p><p></p><p>Z\left(H\right) = 1</p><p></p><p>Z\left(He\right) = 2</p><p></p><p>∴ \lambda\left({He}^{+}\right) = \dfrac{1 \times 91 . 2}{4} = 22 . 8nm

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