Quantrex Quantrex AcademyJEE · NEET · NDA PYQs with solutions Open app
COMEDK2024ChemistryCoordination CompoundsActual

The molar conductivity of the complex CoCl ₃ 4 NH ₃ 2 H ₂ O is found to be the same as that of a 1: 3 electrolyte. The structural formula of the compound is :

Options

  1. A[ Co ( NH ₃ )₄ ( H ₂ O ) Cl ₂ ] Cl H ₂ O
  2. B[ Co ( NH ₃ )₄ Cl ( H ₂ O ) ] Cl ₂ H ₂ O
  3. C[ Co ( NH ₃ )₄ ( H ₂ O )₂ Cl ] Cl ₂
  4. D[ Co ( NH ₃ )₄ ( H ₂ O )₂ ] Cl ₃

Correct answer

D. [ Co ( NH ₃ )₄ ( H ₂ O )₂ ] Cl ₃

Step-by-step solution

The molar conductivity of a 1:3 electrolyte indicates that the complex dissociates into 4 ions in total, consisting of one complex cation and three chloride anions. This implies that all three chloride ions are present outside the coordination sphere as counter ions. The coordination number of Cobalt in such complexes is typically 6 . The formula given is CoCl ₃ 4 NH ₃ 2 H ₂ O . If the complex is a 1:3 electrolyte, the structure must be of the form [ Co ( NH ₃)₄( H ₂ O )₂] Cl ₃ . In this structure, the coordination

Practice Coordination Compounds on Quantrex Academy →

More from Coordination Compounds

Identify the complex which exhibits all 3 characteristics; paramagnetic; high spin configuration; octahedral geometry 2026Which one of the following complex-isomerism pair matches correctly? 2026Match the Coordination compounds in Column I with the type of stereoisomerism given in Column II exhibited by them. Column I Column II A. [ Pt ( NH ₃)₂ Cl ₂] P. fac-mer B. Ni [( NH 2026The Crystal Field Stabilisation energy of (i) [ CoF ₆]³⁻ and (ii) [ Fe ( H ₂ O )₆]³⁺ are ----- and ------- respectively. 2026Which one of the following octahedral complexes has the highest spin-only magnetic moment? 2026Metal-ligand -bond formation in Mn ₂( CO )₁₀ and [ MnO ₄]^- requires electron-pair donation between metal and ligand orbitals. Which one of the following represents the direction o 2026Which of the following is the most stable complex ion? 2026How many ions per molecule are produced from the complex [ Co(NH ₃ ) ₆] Cl ₂ in solution? 2026 Full Coordination Compounds list All COMEDK PYQs