Quantrex Quantrex AcademyJEE · NEET · NDA PYQs with solutions Open app
COMEDK2024Evening ShiftChemistryCoordination CompoundsActual

Given below are 4 statements. Two of these are correct statements. Identify them. A. Co ²⁺ is easily oxidised to Co ³⁺ in the presence of a strong ligand like CN ⁻ B. [ Fe ( CN )₆]⁴⁻ is an octahedral complex ion which is paramagnetic in nature. C. Removal of H ₂ O molecules from [ Ti ( H ₂ O )₆] Cl ₃ on strong heating converts it to a colourless compound. D. Crystal Field splitting in Octahedral and Tetrahedral compl

Options

  1. AC & B
  2. BA & D
  3. CB & D
  4. DA & C

Correct answer

D. A & C

Step-by-step solution

Statement A is correct. In the presence of strong field ligands like CN ⁻ , the crystal field splitting energy is high, which stabilizes the Co ³⁺ oxidation state ( d^6 configuration) over Co ²⁺ ( d^7 configuration) due to the large crystal field stabilization energy (CFSE). Statement B is incorrect. [ Fe ( CN )₆]⁴⁻ contains Fe ²⁺ ( d^6 ). CN ⁻ is a strong field ligand, causing pairing of electrons in the t_ 2g orbitals. Thus, it is diamagnetic, not paramagnetic. Statement C is correct. [ Ti ( H ₂ O )₆] Cl ₃ is a d

Practice Coordination Compounds on Quantrex Academy →

More from Coordination Compounds

Identify the complex which exhibits all 3 characteristics; paramagnetic; high spin configuration; octahedral geometry 2026Which one of the following complex-isomerism pair matches correctly? 2026Match the Coordination compounds in Column I with the type of stereoisomerism given in Column II exhibited by them. Column I Column II A. [ Pt ( NH ₃)₂ Cl ₂] P. fac-mer B. Ni [( NH 2026The Crystal Field Stabilisation energy of (i) [ CoF ₆]³⁻ and (ii) [ Fe ( H ₂ O )₆]³⁺ are ----- and ------- respectively. 2026Which one of the following octahedral complexes has the highest spin-only magnetic moment? 2026Metal-ligand -bond formation in Mn ₂( CO )₁₀ and [ MnO ₄]^- requires electron-pair donation between metal and ligand orbitals. Which one of the following represents the direction o 2026Which of the following is the most stable complex ion? 2026How many ions per molecule are produced from the complex [ Co(NH ₃ ) ₆] Cl ₂ in solution? 2026 Full Coordination Compounds list All COMEDK PYQs