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COMEDK2023ChemistryCoordination Compounds

The complex [ PtCl ₂( en )₂ ]²⁺ ion shows

Options

  1. Astructural isomerism
  2. Bgeometrical isomerism only
  3. Coptical isomerism only
  4. Dgeometrical and optical isomerism

Correct answer

D. geometrical and optical isomerism

Step-by-step solution

[ PtCl ₂( en )₂ ]²⁺ shows both geometrical and optical isomerism as the complex forms cis and trans isomers. trans-isomer doesn't show optical isomerism since it is symmetrical but cis-isomer shows optical isomerism as it is unsymmetrical.

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