COMEDK2023Morning ShiftChemistryCoordination CompoundsActual
The complex [ PtCl ₂( en )₂ ]²⁺ ion shows
Options
- Ageometrical and optical isomerism
- Bgeometrical isomerism only
- Cstructural isomerism
- Doptical isomerism only
Correct answer
A. geometrical and optical isomerism
Step-by-step solution
The complex [ PtCl ₂( en )₂ ]²⁺ has a coordination number of 6, indicating an octahedral geometry. The ligands are two chloride ions and two ethylenediamine (en) molecules, which are bidentate. The complex can exist in two geometrical forms: the cis-isomer and the trans-isomer. In the trans-isomer, the two chloride ligands are at 180 degrees to each other, resulting in a plane of symmetry, which makes it achiral (optically inactive). In the cis-isomer, the two chloride ligands are at 90 degrees to each other. The c