COMEDK20269 May 2026Morning ShiftChemistryElectrochemistryActual
Two statements, one Assertion and the other Reason are given. Choose the right option. Assertion: The Molar conductivity of KCl increases very slowly with dilution and approaches a limiting value when dilution is infinite. Reason: In case of KCl there is an increase in the number of ions on dilution due to complete ionisation at infinite dilution.
Options
- ABoth Assertion and Reason are correct but Reason is not the correct explanation of Assertion
- BBoth Assertion and Reason are correct and Reason is the correct explanation of Assertion
- CAssertion is correct but Reason is incorrect
- DAssertion is incorrect but Reason is correct
Correct answer
C. Assertion is correct but Reason is incorrect
Step-by-step solution
KCl is a strong electrolyte and is completely ionised in solution at all concentrations. Therefore, the number of ions does not increase upon dilution. The molar conductivity of a strong electrolyte like KCl increases slowly with dilution and approaches a limiting value at infinite dilution ( _m^ ). This increase is not due to an increase in the number of ions, but rather due to a decrease in interionic attractions, which increases the mobility of the ions. Thus, the Assertion is correct, but the Reason is incorrec