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COMEDK20269 May 2026Morning ShiftChemistryElectrochemistryActual

Two statements, one Assertion and the other Reason are given. Choose the right option. Assertion: The Molar conductivity of KCl increases very slowly with dilution and approaches a limiting value when dilution is infinite. Reason: In case of KCl there is an increase in the number of ions on dilution due to complete ionisation at infinite dilution.

Options

  1. ABoth Assertion and Reason are correct but Reason is not the correct explanation of Assertion
  2. BBoth Assertion and Reason are correct and Reason is the correct explanation of Assertion
  3. CAssertion is correct but Reason is incorrect
  4. DAssertion is incorrect but Reason is correct

Correct answer

C. Assertion is correct but Reason is incorrect

Step-by-step solution

KCl is a strong electrolyte and is completely ionised in solution at all concentrations. Therefore, the number of ions does not increase upon dilution. The molar conductivity of a strong electrolyte like KCl increases slowly with dilution and approaches a limiting value at infinite dilution ( _m^ ). This increase is not due to an increase in the number of ions, but rather due to a decrease in interionic attractions, which increases the mobility of the ions. Thus, the Assertion is correct, but the Reason is incorrec

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