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COMEDK2015ChemistryElectrochemistry

The standard electrode potential for Daniell cell is 1.1 ~V . What is the standard Gibbs energy for the reaction?

Options

  1. A212.3 ~kJ ~mol ⁻¹
  2. B-2123 ~kJ ~mol ⁻¹
  3. C106.15 ~kJ ~mol ⁻¹
  4. D-106.15 ~kJ ~mol ⁻¹

Correct answer

B. -2123 ~kJ ~mol ⁻¹

Step-by-step solution

Net reaction occuring in a Daniell cell is aligned Zn (s) &+ Cu ²⁺(a q) Zn ²⁺(a q)+ Cu (s) G &=-n F E^ =-2 96500 1.1 &=-212300 ~J ~mol ⁻¹=-212.3 ~kJ ~mol ⁻¹ aligned

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