Quantrex Quantrex AcademyJEE · NEET · NDA PYQs with solutions Open app
COMEDK2013ChemistryElectrochemistry

The standard reduction potentials of Zn and Ag in water at 298 ~K are, aligned Zn ²⁺+2 e⁻ Zn , & E^ =-0.76 ~V and Ag ⁺+e⁻ Ag ; & E^ =+0.80 ~V . aligned Which of the following reactions take place?

Options

  1. AZn ²⁺(a q)+2 Ag (s) 2 Ag ⁺(a q)+ Zn (s)
  2. BZn (s)+2 Ag ⁺(a q) Zn ²⁺(a q)+2 Ag (s)
  3. CZn ²⁺(a q)+ Ag ⁺(a q) Zn (s)+ Ag (s)
  4. DZn (s)+ Ag (s) Zn ²⁺(a q)+ Ag ⁺(a q)

Correct answer

B. Zn (s)+2 Ag ⁺(a q) Zn ²⁺(a q)+2 Ag (s)

Step-by-step solution

For reaction to be spontaneous, E_ cell ^ >0 For option (b), aligned E_ cell ^ o &= (E_ red ⁰ )_ Cathode - (E_ red ⁰ )_ Anode &=0.80-(-0.76)=156 ~V aligned It will be spontaneous reaction E_ cell ^ a >0 .

Practice Electrochemistry on Quantrex Academy →

More from Electrochemistry

Which of the following is always true about a spontaneous cell reaction in a galvanic cell? 2026The G ^o for the reaction, Cd ²⁺(aq) + Zn (s) Zn ²⁺(aq) + Cd (s) is: [E^o_ Cd ²⁺/ Cd = -0.403, E^o_ Zn ²⁺/ Zn = -0.763 V ] 2026Resistance of 0.2 M solution of an electrolyte is 50 . The conductivity of the solution is 1.3 Sm ⁻¹ . If the resistance of 0.4 M solution of the same electrolyte is 260 , its mola 2026Using the data given below, the strongest reducing agent is: E^o_ Cr ₂ O ₇²⁻/ Cr ³⁺ = 1.33 V E^o_ MnO ₄^-/ Mn ²⁺ = 1.51 V E^o_ Cl ₂/ Cl ^- = 1.36 V E^o_ Cr ³⁺/ Cr = -0.74 V 2026The quantity of Ca that can be produced from molten CaCl₂ , with the same quantity of electricity (in coulombs) required to produce 4.8 g of Mg from molten MgCl₂ is: [Atomic mass o 20263.482 10⁻¹ g of Fe gets deposited when an aqueous solution of Ferric sulphate is electrolysed for 20 minutes using a current of "x" amperes. Find "x". (Atomic mass of Fe = 56amu). 2026Consider a Galvanic cell in which the following reactions occurs: Fe ²⁺(aq) + Ag ^+(aq) Fe ³⁺(aq) + Ag (s) . What is the standard potential of the cell? Given: E^0_ ( Ag ^+/ Ag ) = 2026What will be the change in the electrode potential of chromium electrode dipping into chromic sulphate solution, when the electrolyte is diluted 10 times at 25^ C? [ E^0 ( Cr ³⁺/ C 2026 Full Electrochemistry list All COMEDK PYQs