COMEDK2013ChemistryElectrochemistry
The standard reduction potentials of Zn and Ag in water at 298 ~K are, aligned Zn ²⁺+2 e⁻ Zn , & E^ =-0.76 ~V and Ag ⁺+e⁻ Ag ; & E^ =+0.80 ~V . aligned Which of the following reactions take place?
Options
- AZn ²⁺(a q)+2 Ag (s) 2 Ag ⁺(a q)+ Zn (s)
- BZn (s)+2 Ag ⁺(a q) Zn ²⁺(a q)+2 Ag (s)
- CZn ²⁺(a q)+ Ag ⁺(a q) Zn (s)+ Ag (s)
- DZn (s)+ Ag (s) Zn ²⁺(a q)+ Ag ⁺(a q)
Correct answer
B. Zn (s)+2 Ag ⁺(a q) Zn ²⁺(a q)+2 Ag (s)
Step-by-step solution
For reaction to be spontaneous, E_ cell ^ >0 For option (b), aligned E_ cell ^ o &= (E_ red ⁰ )_ Cathode - (E_ red ⁰ )_ Anode &=0.80-(-0.76)=156 ~V aligned It will be spontaneous reaction E_ cell ^ a >0 .