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COMEDK2014Chemistrys Block Elements

Sodium dissolves in liquid NH ₃ to give a deep blue solution. This is due to

Options

  1. Aammoniated Na ⁺
  2. Bammoniated Na ⁻
  3. Cformation of Na ⁺ / Na ⁻ pair
  4. Dammoniated electrons

Correct answer

D. ammoniated electrons

Step-by-step solution

Na +(x+y) NH ₃ [ Na ( NH ₃ )_ x ]⁺+ [e ( NH ₃ )_ y ]⁻ . The deep blue colour of the solution is due to the ammoniated electron which absorbs energy in the visible region of light and thus, imparts blue colour to the solution.

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