Quantrex Quantrex AcademyJEE · NEET · NDA PYQs with solutions Open app
JEE Advanced 2026Paper 2
Exam
JEE Advanced
Year
2026
Paper
Paper 2
Subject
Chemistry
Chapter
Biomolecules

JEE Advanced 2026 · Paper 2 · Chemistry · Biomolecules

The correct statement(s) regarding sugars is(are) Given: Specific...

The correct statement(s) regarding sugars is(are)
Given: Specific rotations of L-(−-)-glucose and L-(++)-fructose are −52.5∘-52.5^\circ and +92.5∘+92.5^\circ, respectively.

Options

  1. AOn treatment with HNO3\text{HNO}_3, gluconic acid is oxidized to saccharic acid, whereas glucose is not oxidized to saccharic acid.
  2. BFructose gives a positive Fehling's test because it isomerises to glucose and another aldohexose in the presence of Fehling's reagent.
  3. CInvert sugar is an equimolar mixture of D-glucose and D-fructose formed after hydrolysis of the corresponding disaccharide.
  4. DSpecific rotation of invert sugar is −40∘-40^\circ.

Correct answer

B. Fructose gives a positive Fehling's test because it isomerises to glucose and another aldohexose in the presence of Fehling's reagent.

Step-by-step solution

Statement (A) is incorrect: Nitric acid (HNO3\text{HNO}_3) is a strong oxidizing agent that oxidizes both glucose and gluconic acid to saccharic acid.

Statement (B) is correct: Fehling's reagent provides an alkaline medium. Under these conditions, fructose (a ketose) undergoes the Lobry de Bruyn-van Ekenstein rearrangement to form an equilibrium mixture of fructose, glucose, and mannose. Glucose and mannose are aldohexoses that readily reduce Fehling's solution, giving a positive test.

Statement (C) is correct: Hydrolysis of sucrose (a disaccharide) yields an equimolar mixture of D-(++)-glucose and D-(−-)-fructose. This mixture is known as invert sugar because the sign of specific rotation changes from positive (for sucrose) to negative (for the mixture).

Statement (D) is incorrect: The specific rotation of L-(−-)-glucose is −52.5∘-52.5^\circ, so for D-(++)-glucose it is +52.5∘+52.5^\circ. The specific rotation of L-(++)-fructose is +92.5∘+92.5^\circ, so for D-(−-)-fructose it is −92.5∘-92.5^\circ.
The specific rotation of invert sugar (an equimolar mixture of D-glucose and D-fructose, which have the same molar mass) is the average of their specific rotations:
[α]mix=+52.5∘+(−92.5∘)2=−20∘[\alpha]_{\text{mix}} = \dfrac{+52.5^\circ + (-92.5^\circ)}{2} = -20^\circ.

Answer: Fructose gives a positive Fehling's test because it isomerises to glucose and another aldohexose in the presence of Fehling's reagent.; Invert sugar is an equimolar mixture of D-glucose and D-fructose formed after hydrolysis of the corresponding disaccharide.
Practice Biomolecules on Quantrex Academy →

More from Biomolecules

A known artificial sweetener X is composed of 4-chloro-4-deoxy- α -D-galactose and… JEE Advanced 2026In the following reaction sequence, major products X and Y are acyclic monomers. 500 mol… JEE Advanced 2026The incorrect statement from the following with respect to carbohydrates is: JEE Main 2026Which of the following amino acid will give violet coloured complex with neutral ferric… JEE Main 2026Consider the following reactions. Total number of electrons in the π bonds and lone pair… JEE Main 2026Match the LIST-I with LIST-II List-I Deficiency Disease List-II Vitamin A. Scurvy I.… JEE Main 2026Match the LIST-I with LIST-II List-I Amino acid List-II Positive reaction/Test for… JEE Main 2026Sucrose hydrolyses in acidic medium into glucose and fructose by first order rate law… JEE Main 2026 Full Biomolecules list All JEE Advanced PYQs