JEE Advanced 2026Paper 2
- Exam
- JEE Advanced
- Year
- 2026
- Paper
- Paper 2
- Subject
- Chemistry
- Chapter
- Biomolecules
JEE Advanced 2026 · Paper 2 · Chemistry · Biomolecules
The correct statement(s) regarding sugars is(are) Given: Specific...
The correct statement(s) regarding sugars is(are)
Given: Specific rotations of L-()-glucose and L-()-fructose are and , respectively.
Given: Specific rotations of L-()-glucose and L-()-fructose are and , respectively.
Options
- AOn treatment with , gluconic acid is oxidized to saccharic acid, whereas glucose is not oxidized to saccharic acid.
- BFructose gives a positive Fehling's test because it isomerises to glucose and another aldohexose in the presence of Fehling's reagent.
- CInvert sugar is an equimolar mixture of D-glucose and D-fructose formed after hydrolysis of the corresponding disaccharide.
- DSpecific rotation of invert sugar is .
Correct answer
B. Fructose gives a positive Fehling's test because it isomerises to glucose and another aldohexose in the presence of Fehling's reagent.
Step-by-step solution
Statement (A) is incorrect: Nitric acid () is a strong oxidizing agent that oxidizes both glucose and gluconic acid to saccharic acid.
Statement (B) is correct: Fehling's reagent provides an alkaline medium. Under these conditions, fructose (a ketose) undergoes the Lobry de Bruyn-van Ekenstein rearrangement to form an equilibrium mixture of fructose, glucose, and mannose. Glucose and mannose are aldohexoses that readily reduce Fehling's solution, giving a positive test.
Statement (C) is correct: Hydrolysis of sucrose (a disaccharide) yields an equimolar mixture of D-()-glucose and D-()-fructose. This mixture is known as invert sugar because the sign of specific rotation changes from positive (for sucrose) to negative (for the mixture).
Statement (D) is incorrect: The specific rotation of L-()-glucose is , so for D-()-glucose it is . The specific rotation of L-()-fructose is , so for D-()-fructose it is .
The specific rotation of invert sugar (an equimolar mixture of D-glucose and D-fructose, which have the same molar mass) is the average of their specific rotations:
.
Answer: Fructose gives a positive Fehling's test because it isomerises to glucose and another aldohexose in the presence of Fehling's reagent.; Invert sugar is an equimolar mixture of D-glucose and D-fructose formed after hydrolysis of the corresponding disaccharide.
Statement (B) is correct: Fehling's reagent provides an alkaline medium. Under these conditions, fructose (a ketose) undergoes the Lobry de Bruyn-van Ekenstein rearrangement to form an equilibrium mixture of fructose, glucose, and mannose. Glucose and mannose are aldohexoses that readily reduce Fehling's solution, giving a positive test.
Statement (C) is correct: Hydrolysis of sucrose (a disaccharide) yields an equimolar mixture of D-()-glucose and D-()-fructose. This mixture is known as invert sugar because the sign of specific rotation changes from positive (for sucrose) to negative (for the mixture).
Statement (D) is incorrect: The specific rotation of L-()-glucose is , so for D-()-glucose it is . The specific rotation of L-()-fructose is , so for D-()-fructose it is .
The specific rotation of invert sugar (an equimolar mixture of D-glucose and D-fructose, which have the same molar mass) is the average of their specific rotations:
.
Answer: Fructose gives a positive Fehling's test because it isomerises to glucose and another aldohexose in the presence of Fehling's reagent.; Invert sugar is an equimolar mixture of D-glucose and D-fructose formed after hydrolysis of the corresponding disaccharide.