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JEE Advanced 2026Paper 2
Exam
JEE Advanced
Year
2026
Paper
Paper 2
Subject
Chemistry
Chapter
Biomolecules

JEE Advanced 2026 · Paper 2 · Chemistry · Biomolecules

In the following reaction sequence, major products X and Y are...

In the following reaction sequence, major products X\textbf{X} and Y\textbf{Y} are acyclic monomers.
In the following reaction sequence, major products X and Y are acyclic monomers. 500 mol of X completely reacts with
500500 mol of X\textbf{X} completely reacts with 500500 mol of Y\textbf{Y} to give 11 mol of a single biodegradable acyclic copolymer Z\textbf{Z} as the only product. The amount of Z\textbf{Z} formed in grams is ____.
Given:
Atomic mass (in amu): H : 11, C : 1212, N : 1414, O : 1616, Br : 8080

Correct answer

0

Step-by-step solution

Step 1: Identification of monomer X\textbf{X}
The given reaction sequence for X\textbf{X} is:
CH3I→KCNCH3CN\text{CH}_3\text{I} \xrightarrow{\text{KCN}} \text{CH}_3\text{CN}
CH3CN→H3O+,ΔCH3COOH\text{CH}_3\text{CN} \xrightarrow{\text{H}_3\text{O}^+, \Delta} \text{CH}_3\text{COOH}
CH3COOH→Red P, Br2BrCH2COOH\text{CH}_3\text{COOH} \xrightarrow{\text{Red P, Br}_2} \text{BrCH}_2\text{COOH} (Hell-Volhard-Zelinsky reaction)
BrCH2COOH→NH3 (excess)H2N−CH2−COOH\text{BrCH}_2\text{COOH} \xrightarrow{\text{NH}_3 \text{ (excess)}} \text{H}_2\text{N}-\text{CH}_2-\text{COOH}
Thus, X\textbf{X} is Glycine.
Molar mass of X\textbf{X} (C2H5NO2\text{C}_2\text{H}_5\text{NO}_2) = 2(12)+5(1)+14+2(16)=75 g/mol2(12) + 5(1) + 14 + 2(16) = 75 \text{ g/mol}.

Step 2: Identification of monomer Y\textbf{Y}
Caprolactam on acidic hydrolysis gives ϵ\epsilon-aminocaproic acid:
Caprolactam →H3O+,ΔH2N−(CH2)5−COOH\xrightarrow{\text{H}_3\text{O}^+, \Delta} \text{H}_2\text{N}-(\text{CH}_2)_5-\text{COOH}
Thus, Y\textbf{Y} is ϵ\epsilon-aminocaproic acid.
Molar mass of Y\textbf{Y} (C6H13NO2\text{C}_6\text{H}_{13}\text{NO}_2) = 6(12)+13(1)+14+2(16)=131 g/mol6(12) + 13(1) + 14 + 2(16) = 131 \text{ g/mol}.

Step 3: Calculation of the mass of copolymer Z\textbf{Z}
The copolymer Z\textbf{Z} is Nylon-2-nylon-6, which is a biodegradable polyamide formed by the condensation polymerization of Glycine and ϵ\epsilon-aminocaproic acid.
The problem states that 500 mol500 \text{ mol} of X\textbf{X} and 500 mol500 \text{ mol} of Y\textbf{Y} completely react to form 1 mol1 \text{ mol} of a single acyclic copolymer Z\textbf{Z}.
This means each molecule of polymer Z\textbf{Z} contains 500500 units of X\textbf{X} and 500500 units of Y\textbf{Y}, making a total of 10001000 monomer units.
In an acyclic chain of 10001000 monomers, the number of peptide (amide) bonds formed is 1000−1=9991000 - 1 = 999.
For each peptide bond formed, one molecule of water (H2O\text{H}_2\text{O}) is eliminated. Since 1 mol1 \text{ mol} of polymer Z\textbf{Z} is formed, 999 mol999 \text{ mol} of water are eliminated.

Applying the law of conservation of mass:
Mass of Z\textbf{Z} = (Mass of 500 mol500 \text{ mol} of X\textbf{X}) + (Mass of 500 mol500 \text{ mol} of Y\textbf{Y}) - (Mass of 999 mol999 \text{ mol} of H2O\text{H}_2\text{O})
Mass of Z=(500×75)+(500×131)−(999×18)\textbf{Z} = (500 \times 75) + (500 \times 131) - (999 \times 18)
Mass of Z=37500+65500−17982\textbf{Z} = 37500 + 65500 - 17982
Mass of Z=103000−17982=85018 g\textbf{Z} = 103000 - 17982 = 85018 \text{ g}

Answer: 8501885018
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