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JEE Advanced2018ChemistryHaloalkanes and HaloarenesActual

List-I contains reactions and List-II contains major products List-I List-II A) P) B) Q) C) R) D) S) T) Match each reaction in List-I with one or more products in List-II and choose the correct option

Options

  1. Aa-s,t;b-s;c-q,r;d-q,r,s;
  2. Ba-r,s,t;b-r;c-s,t;d-s,t;
  3. Ca-p,s;b-q;c-s;d-r;
  4. Da-q;b-s,t;c-r;d-t;

Correct answer

C. a-p,s;b-q;c-s;d-r;

Step-by-step solution

( A ) Bulky base is present, it will abstract proton, hence will undergo E2 reaction ( B ) Hydrogen ion will protonate the oxygen of methoxy group and make it a good leaving group, hence methanol and t-butyl bromide is formed. ( C ) Methoxy group will abstract proton. E2 elimination occur ( D ) It will undergo S N 2 mechanism.

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