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JEE Advanced 2008Paper 1
Exam
JEE Advanced
Year
2008
Paper
Paper 1
Subject
Chemistry
Chapter
Haloalkanes and Haloarenes

JEE Advanced 2008 · Paper 1 · Chemistry · Haloalkanes and Haloarenes

The major product of the following reaction is

The major product of the following reaction is The major product of the following reaction is

Options

  1. AAmong the following, the group of molecules that undergoes rapid hydrolysis is
  2. BAmong the following, the group of molecules that undergoes rapid hydrolysis is
  3. CAmong the following, the group of molecules that undergoes rapid hydrolysis is
  4. DAmong the following, the group of molecules that undergoes rapid hydrolysis is

Correct answer

A. Among the following, the group of molecules that undergoes rapid hydrolysis is

Step-by-step solution

PhS−\mathrm{PhS}^{-}is a strong nucleophile and dimethylformamide (DMF) is a highly polar aprotic solvent. Condition indicates that nucleophilic substitution (SN2)\left(\mathrm{S}_{\mathrm{N}} 2\right) takes place at 2∘2^{\circ} benzylic place, stereochemically it involves inversion of configuration. The major product of the following reaction is
Aryl group can exhibit neighbouring group or can show anchimeric assistance but not possible here due to deactivity imparted by −NO2and−F-\mathrm{NO}_2 and -\mathrm{F}. It can be if −OCH3-\mathrm{OCH}_3 would have been instead of −NO2-\mathrm{NO}_2.The major product of the following reaction is
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