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JEE Advanced 2023Paper 2
Exam
JEE Advanced
Year
2023
Paper
Paper 2
Subject
Chemistry
Chapter
Redox Reactions

JEE Advanced 2023 · Paper 2 · Chemistry · Redox Reactions

H _ 2 S ( 5 moles) reacts completely with acidified aqueous...

H2S{H}_{2}S (55 moles) reacts completely with acidified aqueous potassium permanganate solution. In this reaction, the number of moles of water produced is xx, and the number of moles of electrons involved is yy. The value of (x+y)( x + y ) is

Correct answer

0

Step-by-step solution

KMnO4⟶H+Mn2+{KMnO}_{4}\overset{{H}^{+}}{⟶}{Mn}^{2 +}

S−2⟶S0{S}^{- 2} ⟶ \overset{0}{S}

The number of electrons involved per molecule is called n-factor.

n-factor of KMnO4=5{KMnO}_{4} = 5

n-factor of S−2(H2S)=2{S}^{- 2}\left({H}_{2}S\right) = 2

Moles \times n - factor = numberofequivalents</p><p>(nKMnO4×5)=(5×2)H2S</p><p>\left({n}_{{KMnO}_{4}} \times 5\right) = ( 5 \times 2{)}_{{H}_{2}S}

∴nKMnO4=2∴ {n}_{{KMnO}_{4}} = 2

∴2KMnO4+3H2SO4+5H2S→K2SO4+2MnSO4+5S+8H2O∴ 2{KMnO}_{4} + 3{H}_{2}{SO}_{4} + 5{H}_{2}S \to {K}_{2}{SO}_{4} + 2{MnSO}_{4} + 5S + 8{H}_{2}O

Number of moles of water produced =8= 8

Number of moles of electrons involved =10= 10

∴ x = 8, y = 10 ⇒ ( x + y ) = 18

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