JEE Main 20262 AprilEvening Shift
- Exam
- JEE Main
- Year
- 2026
- Date
- 2 April
- Shift
- Evening Shift
- Subject
- Chemistry
- Chapter
- Aldehydes and Ketones
JEE Main 2026 · 2 April · Evening Shift · Chemistry · Aldehydes and Ketones
An organic compound " x " where molar ratio of C, O and H are...
An organic compound "" where molar ratio of C, O and H are equal, on treatment with KOH under reflux followed by acidification produced "". The most likely structure of "" is:
[Molar mass of '' is g mol]
[Molar mass of '' is g mol]
Options
- A
- B
- C (with C-C bond)
- D
Correct answer
C. (with C-C bond)
Step-by-step solution
Given the molar ratio of C, O, and H in compound is equal, the empirical formula is .
Empirical mass g mol.
Since the molar mass of is g mol, the molecular formula is or .
The structure of is glyoxal, .
Treatment of glyoxal with KOH under reflux results in an intramolecular Cannizzaro reaction. One aldehyde group is oxidized to a carboxylate ion, and the other is reduced to a primary alcohol.
Subsequent acidification yields glycolic acid ().
The structure of is .
Answer: (with C-C bond)
Empirical mass g mol.
Since the molar mass of is g mol, the molecular formula is or .
The structure of is glyoxal, .
Treatment of glyoxal with KOH under reflux results in an intramolecular Cannizzaro reaction. One aldehyde group is oxidized to a carboxylate ion, and the other is reduced to a primary alcohol.
Subsequent acidification yields glycolic acid ().
The structure of is .
Answer: (with C-C bond)