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JEE Main 20198 AprilEvening Shift
Exam
JEE Main
Year
2019
Date
8 April
Shift
Evening Shift
Subject
Chemistry
Chapter
Chemical Equilibrium

JEE Main 2019 · 8 April · Evening Shift · Chemistry · Chemical Equilibrium

For the following reaction, equilibrium constant are given: S(s) +...

For the following reaction, equilibrium constant are given:

S(s)+O2(g)⇌SO2(g);K1=1052S\left(s\right) + {O}_{2}\left(g\right) ⇌ S{O}_{2}\left(g\right); {K}_{1} = {10}^{52}

2S(s)+3O2(g)⇌2SO3(g);K2=101292S\left(s\right) + 3{O}_{2}\left(g\right) ⇌ 2S{O}_{3}\left(g\right); {K}_{2} = {10}^{129}

The equilibrium constant for the reaction, 2SO2(g)+O2(g)⇌2SO3(g)2{SO}_{2}\left(g\right) + {O}_{2}\left(g\right) ⇌ 2S{O}_{3}\left(g\right) is:

Options

  1. A10154{10}^{154}
  2. B1025{10}^{25}
  3. C10181{10}^{181}
  4. D1077{10}^{77}

Correct answer

B. 1025{10}^{25}

Step-by-step solution

S(s)+O2(g)⇌SO2(g)\left(s\right) + {O}_{2}\left(g\right) ⇌ S{O}_{2}\left(g\right); {k}_{1} = {10}^{52}&hellip;&hellip;(i)</p><p>2S\left(s\right) + 3{O}_{2}\left(g\right) ⇌ S{O}_{2}\left(g\right); {k}_{2} = {10}^{129}&hellip;&hellip;(ii)</p><p>2S{O}_{2}\left(g\right) + {O}_{2}\left(g\right) ⇌ 2S{O}_{3}\left(g\right); {k}_{eq} = ?</p><p></p><p>{k}_{eq} = \dfrac{{\left[S{O}_{3}\right]}^{2}}{{\left[S{O}_{2}\right]}^{2}\left[{O}_{2}\right]}</p><p></p><p>{k}_{1} = \dfrac{\left[S{O}_{2}\right]}{\left[{O}_{2}\right]} = {10}^{52}</p><p></p><p>{k}_{2} = \dfrac{{\left[S{O}_{3}\right]}^{2}}{{\left[{O}_{2}\right]}^{3}} = {10}^{129}</p><p></p><p>{k}_{eq} = \dfrac{{k}_{2}}{{\left({k}_{1}\right)}^{2}} = \dfrac{{10}^{129}}{{\left({10}^{52}\right)}^{2}} = {10}^{25}

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