- Exam
- JEE Main
- Year
- 2022
- Date
- 25 June
- Shift
- Evening Shift
- Subject
- Chemistry
- Chapter
- General Principles and Processes of Isolation of Metals
JEE Main 2022 · 25 June · Evening Shift · Chemistry · General Principles and Processes of Isolation of Metals
Given below are two statements. Statement I: During electrolytic...
Given below are two statements.
Statement I: During electrolytic refining. blister copper deposits precious metals.
Statement II: In the process of obtaining pure copper by electrolysis method, copper blister is used to make the anode.
In the light of the above statements, choose the correct answer from the options given below.
Options
- ABoth Statement I and Statement II are true.
- BBoth Statement I and Statement II are false.
- CStatement I is true but Statement II is false.
- DStatement I is false but Statement II is true.
Correct answer
A. Both Statement I and Statement II are true.
Step-by-step solution
Impure obtained from ores is converted to pure in an electrolyte cell that the impure copper as the anode an pure copper as the cathode. The electrolyte is an aqueous solution of . At the impure anode, is oxidized along with the more easily oxidized metallic impurities such as and Fe. The less easily oxidized impurities such as , and fall to the bottom of the cell as anode mud, which is reprocessed to recover the precious metals. At the pure cathode, ions get reduced to pure copper metal
Anode (oxidation) :
Cathode (reduction) :
Thus, the net cell reaction simply involves transfer of metal from the impure anode to the pure cathode, obtained by this process is pure.