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JEE Main 202225 JuneEvening Shift
Exam
JEE Main
Year
2022
Date
25 June
Shift
Evening Shift
Subject
Chemistry
Chapter
General Principles and Processes of Isolation of Metals

JEE Main 2022 · 25 June · Evening Shift · Chemistry · General Principles and Processes of Isolation of Metals

Given below are two statements. Statement I: During electrolytic...

Given below are two statements.

Statement I: During electrolytic refining. blister copper deposits precious metals.

Statement II: In the process of obtaining pure copper by electrolysis method, copper blister is used to make the anode.

In the light of the above statements, choose the correct answer from the options given below.

Options

  1. ABoth Statement I and Statement II are true.
  2. BBoth Statement I and Statement II are false.
  3. CStatement I is true but Statement II is false.
  4. DStatement I is false but Statement II is true.

Correct answer

A. Both Statement I and Statement II are true.

Step-by-step solution

Impure CuCu obtained from ores is converted to pure CuCu in an electrolyte cell that the impure copper as the anode an pure copper as the cathode. The electrolyte is an aqueous solution of CuSO4{CuSO}_{4}. At the impure CuCu anode, CuCu is oxidized along with the more easily oxidized metallic impurities such as ZnZn and Fe. The less easily oxidized impurities such as Ag,AuAg, Au, and PtPt fall to the bottom of the cell as anode mud, which is reprocessed to recover the precious metals. At the pure CuCu cathode, Cu2+{Cu}^{2 +} ions get reduced to pure copper metal

Anode (oxidation) : M(s)⟶M2+(aq)+2e−(M=Cu,Zn,Fe)M\left(s\right) ⟶ {M}^{2 +}\left(aq\right) + 2{e}^{-}\left(M = Cu, Zn, Fe\right)

Cathode (reduction) : Cu2+(aq)+2e−⟶Cu(s){Cu}^{2 +}\left(aq\right) + 2{e}^{-} ⟶ Cu\left(s\right)

Thus, the net cell reaction simply involves transfer of CuCu metal from the impure anode to the pure cathode, CuCu obtained by this process is 99.9599 . 95 % pure.

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