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JEE Main202622 January 2026Morning ShiftChemistryHaloalkanes and HaloarenesActual

As compared with chlorocyclohexane, which of the following statements correctly apply to chlorobenzene? A. The magnitude of negative charge is more on chlorine atom. B. The C - Cl bond has partial double bond character. C. C - Cl bond is less polar. D. C - Cl bond is longer due to repulsion between delocalised electrons of the aromatic ring and lone pairs of electrons of chlorine. E. The C - Cl bond is formed using s

Options

  1. AB, C and E Only
  2. BA, C and E Only
  3. CA, D and E Only
  4. DB, C and D Only

Correct answer

A. B, C and E Only

Step-by-step solution

Chlorobenzene has Cl attached to an sp² carbon of the benzene ring, while chlorocyclohexane has Cl attached to an sp³ carbon. Statement B is correct: the C-Cl bond has partial double bond character due to resonance with the aromatic π system, where chlorine's lone pairs interact with the aromatic ring. Statement C is correct: the C-Cl bond is less polar in chlorobenzene because the resonance contribution reduces the electronegativity difference between C and Cl. Statement E is correct: the C-Cl bond is formed using

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