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JEE Main 202427 JanuaryEvening Shift
Exam
JEE Main
Year
2024
Date
27 January
Shift
Evening Shift
Subject
Chemistry
Chapter
Haloalkanes and Haloarenes

JEE Main 2024 · 27 January · Evening Shift · Chemistry · Haloalkanes and Haloarenes

Which among the following halide/s will not show S _ N 1 reaction:

Which among the following halide/s will not show SN1{S}_{N}1 reaction:Which among the following halide/s will not show S _ N 1 reaction:Which among the following halide/s will not show S _ N 1 reaction:

Options

  1. AH2C=CH−CH2Cl{H}_{2}C = CH - {CH}_{2}Cl
  2. BCH3−CH=CH−Cl{CH}_{3} - CH = CH - Cl
  3. CThe correct orders among the following are Atomic radius : B Al Ga In Tl Electronegativity : Al Ga In Tl B Density : Tl
  4. DThe correct orders among the following are Atomic radius : B Al Ga In Tl Electronegativity : Al Ga In Tl B Density : Tl

Correct answer

B. CH3−CH=CH−Cl{CH}_{3} - CH = CH - Cl

Step-by-step solution

Vinylic halides are organic compounds containing their halogen atom bonded to one of the two carbon atoms in the double bond present in that molecule.

Vinyl halide will not show SN1{S}_{N}1 reaction, due to very
less stability of carbocation formed and partial
double bond character in C — Cl bond.

Since CH3−CH=C+H{CH}_{3} - CH = \overset{+}{C}H is very unstable, CH3−CH={CH}_{3} - CH = CH−ClCH - Cl cannot give SN1{S}_{N}1 reaction.

Hence, the answer is B.

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