- Exam
- JEE Main
- Year
- 2023
- Date
- 13 April
- Shift
- Morning Shift
- Subject
- Chemistry
- Chapter
- Haloalkanes and Haloarenes
JEE Main 2023 · 13 April · Morning Shift · Chemistry · Haloalkanes and Haloarenes
2 - Methyl propyl bromide reacts with C _ 2 H _ 5 O ^ - and gives ‘...
Methyl propyl bromide reacts with and gives whereas on reaction with it gives The mechanism followed in these reactions and the products and respectively are:
Options
- A
iso-butyl ethyl ether;tert-butyl ethyl ether
- B
tert-butyl ethyl ether; butyl ethyl ether
- C
butyl ethyl ether; iso-butyl ethyl ether
- D
tert-butyl ethyl ether; iso-butyl ethyl ether
Correct answer
A.
iso-butyl ethyl ether;tert-butyl ethyl ether
Step-by-step solution
The reaction between methyl propyl bromide and proceeds via an (substitution nucleophilic bimolecular) mechanism. In this mechanism, the nucleophile attacks the carbon atom bearing the bromine (the electrophilic carbon) in a single step, leading to the displacement of the bromine atom.
The reaction between methyl propyl bromide and can proceed via either an (substitution nucleophilic unimolecular). Here is a weak nucleophile. During the reaction 1,2-hydrogen shift will occur and tert-butyl ethyl ether is formed.