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JEE Main 202331 JanuaryEvening Shift
Exam
JEE Main
Year
2023
Date
31 January
Shift
Evening Shift
Subject
Chemistry
Chapter
Haloalkanes and Haloarenes

JEE Main 2023 · 31 January · Evening Shift · Chemistry · Haloalkanes and Haloarenes

In the following halogenated organic compounds the one with maximum...

In the following halogenated organic compounds the one with maximum number of chlorine atoms in its structure is:

Options

  1. AChloral
  2. BGammaxene
  3. CChloropicrin
  4. DFreon-1212

Correct answer

B. Gammaxene

Step-by-step solution

Percentage of chlorine content = mass of  chlorinemass of organic compound×100\dfrac{\text{mass\text{ of } chlorine}}{\text{mass of organic compound}} \times 100

(A) Chloral (CCl3CHO)( {CCl}_{3}CHO ):

Percentage of chlorine content = 3×35.5147.5×100=72.203\dfrac{3 \times 35 . 5}{147 . 5} \times 100 = 72 . 203 %

(B) Gammaxene \left({C}_{6}{H}_{6}{Cl}_{6}\right):</p><p>Percentageofchlorinecontent=:</p><p>Percentage of chlorine content =\dfrac{6 \times 35 . 5}{291} \times 100 = 73 . 2 %</p><p>(C)Chloropicrin</p><p>(C) Chloropicrin{Cl}_{3}C – {NO}_{2}:</p><p>Percentageofchlorinecontent=:</p><p>Percentage of chlorine content =\dfrac{3 \times 35 . 5}{165} \times 100 = 64 . 54 %</p><p>(D)Freon−</p><p>(D) Freon-12 \left({CF}_{2}{Cl}_{2}\right):

Percentageofofchlorine content = \dfrac{2 \times 35 . 5}{121} \times 100 = 58 . 67 %

As per the percentage of chlorine, Gammaxene has the maximum number of chlorine atoms.

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