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JEE Main 202330 JanuaryMorning Shift
Exam
JEE Main
Year
2023
Date
30 January
Shift
Morning Shift
Subject
Chemistry
Chapter
Haloalkanes and Haloarenes

JEE Main 2023 · 30 January · Morning Shift · Chemistry · Haloalkanes and Haloarenes

Match List I with List II List I List II A I Fittig reaction B II...

Match List I with List II

List I List II
A Match List I with List II List I List II A I Fittig reaction B II Wurtz Fittig reaction C III Finkelstein reaction D C I Fittig reaction
B Match List I with List II List I List II A I Fittig reaction B II Wurtz Fittig reaction C III Finkelstein reaction D C II Wurtz Fittig reaction
C Match List I with List II List I List II A I Fittig reaction B II Wurtz Fittig reaction C III Finkelstein reaction D C III Finkelstein reaction
D C2H5Cl+NaI→C2H5I+Nacl{C}_{2}{H}_{5}Cl + NaI \to {C}_{2}{H}_{5}I + Nacl IV Sandmeyer reaction

Options

  1. AA–II, B–I, C–III, D–IV
  2. BA–III, B–II, C–IV, D–I
  3. CA–IV, B–II, C–III, D–I
  4. DA–II, B–I, C–IV, D–III

Correct answer

D. A–II, B–I, C–IV, D–III

Step-by-step solution

(i) Fittig reaction: Aryl halides give analogous compounds when treated with sodium in dry ether, in which two aryl groups are joined together. It is called Fittig reaction.

(ii) Wurtz-Fittig reaction: A mixture of an alkyl halide and aryl halide gives an alkylarene when treated with sodium in dry ether and is called Wurtz-Fittig reaction.

(iii) Finkelstein reaction: Alkyl iodides are often prepared by the reaction of alkyl chlorides/ bromides with NaI in dry acetone. This reaction is known as Finkelstein reaction.

(iv) Sandmeyer reaction: When a primary aromatic amine, dissolved or suspended in cold aqueous mineral acid, is treated with sodium nitrite, a diazonium salt is formed. Mixing the solution of freshly prepared diazonium salt with cuprous chloride or cuprous bromide results in the replacement of the diazonium group by –Cl or –Br

Hence, the correct matching is given in the below table:

List I List II
A
Match List I with List II List I List II A I Fittig reaction B II Wurtz Fittig reaction C III Finkelstein reaction D C

Wurtz Fitting reaction

B Match List I with List II List I List II A I Fittig reaction B II Wurtz Fittig reaction C III Finkelstein reaction D C Fitting reaction
C Match List I with List II List I List II A I Fittig reaction B II Wurtz Fittig reaction C III Finkelstein reaction D C

Sandmeyer reaction

D C2H5Cl+NaI→C2H5I+Nacl{C}_{2}{H}_{5}Cl + NaI \to {C}_{2}{H}_{5}I + Nacl Finkelstein reaction
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