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JEE Main 201419 AprilOnline
Exam
JEE Main
Year
2014
Date
19 April
Mode
Online
Subject
Chemistry
Chapter
Haloalkanes and Haloarenes

JEE Main 2014 · 19 April · Online · Chemistry · Haloalkanes and Haloarenes

The major product formed when 1, 1, 1- trichloropropane is treated...

The major product formed when 1, 1, 1- trichloropropane is treated with aqueous potassium hydroxide is :The major product formed when 1, 1, 1- trichloropropane is treated with aqueous potassium hydroxide is :The major product formed when 1, 1, 1- trichloropropane is treated with aqueous potassium hydroxide is :

Options

  1. A2 - Propanol
  2. BPropyne
  3. CPropionic acid
  4. D1 - Propanol

Correct answer

C. Propionic acid

Step-by-step solution

The major product formed when 1, 1, 1-trichloro-propane is treated with aqueous potassium hydroxide is propionic acid.

Alc. KOH causes elimination in the molecule of haloalkane generally, while aq. KOH leads to substitution. Here aqueous KOH is used, substitution reaction is most preferable.

The initial reaction is the nucleophilic substitution, which will form a trihydroxy compound, since, three hydroxy group on one carbon is unstable and result in dehydration and form carboxylic acid.

The major product formed when 1, 1, 1- trichloropropane is treated with aqueous potassium hydroxide is :The major product formed when 1, 1, 1- trichloropropane is treated with aqueous potassium hydroxide is :

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