JEE Main 20265 AprilMorning Shift
- Exam
- JEE Main
- Year
- 2026
- Date
- 5 April
- Shift
- Morning Shift
- Subject
- Chemistry
- Chapter
- Hydrocarbons
JEE Main 2026 · 5 April · Morning Shift · Chemistry · Hydrocarbons
For the following Friedel Craft's alkylation reaction, which of the...
For the following Friedel Craft's alkylation reaction, which of the statements are correct?

A. Major product is n-propyl benzene.
B. iso-propyl carbocation intermediate is also generated.
C. Multiple substitution is inevitable.
D. Introducing electron-donating substituent on benzene will not produce any alkyl benzene.
Choose the correct answer from the options given below:
A. Major product is n-propyl benzene.
B. iso-propyl carbocation intermediate is also generated.
C. Multiple substitution is inevitable.
D. Introducing electron-donating substituent on benzene will not produce any alkyl benzene.
Choose the correct answer from the options given below:
Options
- AA and D only
- BB and C only
- CA and C only
- DB and D only
Correct answer
B. B and C only
Step-by-step solution
In the given Friedel-Crafts alkylation reaction, -chloropropane reacts with anhydrous to initially form a primary carbocation, the -propyl carbocation ().
This primary carbocation is less stable and undergoes a -hydride shift to form a more stable secondary carbocation, the iso-propyl carbocation (). Therefore, statement B is correct.
The iso-propyl carbocation then acts as an electrophile and attacks the benzene ring, yielding iso-propylbenzene (cumene) as the major product. Thus, statement A is incorrect.
Once an alkyl group is introduced to the benzene ring, it acts as an electron-donating group (via hyperconjugation and inductive effect), which activates the ring. This makes the newly formed alkylbenzene more reactive towards electrophilic aromatic substitution than the original benzene molecule, leading to polyalkylation. Hence, multiple substitution is a common and inevitable drawback. Therefore, statement C is correct.
Introducing an electron-donating substituent on benzene generally activates the ring and facilitates Friedel-Crafts alkylation (except for strong Lewis bases like which complex with ). Thus, statement D is incorrect.
Therefore, only statements B and C are correct.
Answer: B and C only
This primary carbocation is less stable and undergoes a -hydride shift to form a more stable secondary carbocation, the iso-propyl carbocation (). Therefore, statement B is correct.
The iso-propyl carbocation then acts as an electrophile and attacks the benzene ring, yielding iso-propylbenzene (cumene) as the major product. Thus, statement A is incorrect.
Once an alkyl group is introduced to the benzene ring, it acts as an electron-donating group (via hyperconjugation and inductive effect), which activates the ring. This makes the newly formed alkylbenzene more reactive towards electrophilic aromatic substitution than the original benzene molecule, leading to polyalkylation. Hence, multiple substitution is a common and inevitable drawback. Therefore, statement C is correct.
Introducing an electron-donating substituent on benzene generally activates the ring and facilitates Friedel-Crafts alkylation (except for strong Lewis bases like which complex with ). Thus, statement D is incorrect.
Therefore, only statements B and C are correct.
Answer: B and C only