The arenium ion which is not involved in the bromination of Aniline...

Arenium ion: A carbocation formed by electrophilic attack on an aromatic ring, it is a reactive intermediate in electrophilic aromatic substitution. The formation of an arenium ion takes place by electrophilic attack on benzene.

As the delocalisation of electrons stops at an ${sp}^{3}$ hybridized carbon atom, the arenium ion is not aromatic in nature. 

Since $- \overset{¨}{N}{H}_{2}$ group is $o / p$ directing hence arenium ion will not be formed by attack at meta position i.e.

Hence, the answer is C.