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Concepts Of Physics MCQ Edition [Volume 2]
Exam
Concepts Of Physics MCQ Edition [Volume 2]
Subject
Physics
Chapter
Laws of Thermodynamics

Concepts Of Physics MCQ Edition [Volume 2] · Physics · Laws of Thermodynamics

A cylindrical tube of volume V having adiabatic walls contains an...

A cylindrical tube of volume VV having adiabatic walls contains an ideal gas. The internal energy of this ideal gas is given by 1.5nRT1.5 nRT. A fixed diathermic wall divides the tube into two equal parts. Initially, the pressure and temperature are p1,T1p_1, T_1 on the left side and p2,T2p_2, T_2 on the right side. The system is allowed sufficient time for the temperatures on both sides to become equal. Calculate the amount of heat that has flown from the gas on the right to the gas on the left. (Let λ=p1T2+p2T1\lambda = p_1 T_2 + p_2 T_1)
A cylindrical tube of volume V having adiabatic walls contains an ideal gas. The internal energy of this ideal gas is

Options

  1. A3p1p2(T2+T1)V4λ\dfrac{3 p_1 p_2 (T_2 + T_1) V}{4 \lambda}
  2. B3p1p2(T2−T1)V4λ\dfrac{3 p_1 p_2 (T_2 - T_1) V}{4 \lambda}
  3. C3p1p2(T2−T1)V2λ\dfrac{3 p_1 p_2 (T_2 - T_1) V}{2 \lambda}
  4. Dp1p2(T2−T1)V4λ\dfrac{p_1 p_2 (T_2 - T_1) V}{4 \lambda}

Correct answer

B. 3p1p2(T2−T1)V4λ\dfrac{3 p_1 p_2 (T_2 - T_1) V}{4 \lambda}

Step-by-step solution

Let the volume of each part be V1=V2=V2V_1 = V_2 = \dfrac{V}{2}.

The number of moles of gas in the left and right parts are respectively:
n1=p1(V/2)RT1=p1V2RT1n_1 = \dfrac{p_1 (V/2)}{R T_1} = \dfrac{p_1 V}{2 R T_1}
n2=p2(V/2)RT2=p2V2RT2n_2 = \dfrac{p_2 (V/2)}{R T_2} = \dfrac{p_2 V}{2 R T_2}

The internal energy of the ideal gas is given as U=1.5nRT=32nRTU = 1.5 nRT = \dfrac{3}{2} nRT. This implies the molar heat capacity at constant volume is Cv=32RC_v = \dfrac{3}{2} R.

Since the outer walls are adiabatic and the total volume is fixed, the total internal energy of the system remains conserved.
U1+U2=U1f+U2fU_1 + U_2 = U_{1f} + U_{2f}
n1CvT1+n2CvT2=(n1+n2)CvTfn_1 C_v T_1 + n_2 C_v T_2 = (n_1 + n_2) C_v T_f

Substituting the values of n1andn_1 andn_2:<br>:<br>\dfrac{p_1 V}{2 R T_1} T_1 + \dfrac{p_2 V}{2 R T_2} T_2 = \left( \dfrac{p_1 V}{2 R T_1} + \dfrac{p_2 V}{2 R T_2} \right) T_f<br><br>p_1 + p_2 = \left( \dfrac{p_1 T_2 + p_2 T_1}{T_1 T_2} \right) T_f<br><br>Given<br><br>Given\lambda = p_1 T_2 + p_2 T_1,wecanwrite:<br>, we can write:<br>T_f = \dfrac{(p_1 + p_2) T_1 T_2}{\lambda}<br><br>Theheatflownfromtherightgastotheleftgasisequaltothechangeininternalenergyoftheleftgas(sincethevolumeofeachpartisfixed,workdone<br><br>The heat flown from the right gas to the left gas is equal to the change in internal energy of the left gas (since the volume of each part is fixed, work doneW = 0).<br>).<br>\Delta Q = \Delta U_1 = n_1 C_v (T_f - T_1)<br><br>\Delta Q = \dfrac{p_1 V}{2 R T_1} \left( \dfrac{3}{2} R \right) (T_f - T_1) = \dfrac{3 p_1 V}{4 T_1} (T_f - T_1)<br><br>Now,substitutingthevalueof<br><br>Now, substituting the value ofT_f:<br>:<br>T_f - T_1 = \dfrac{(p_1 + p_2) T_1 T_2}{\lambda} - T_1 = T_1 \left(\dfrac{p_1 T_2 + p_2 T_2 - (p_1 T_2 + p_2 T_1)}{\lambda} \right)
T_f - T_1 = T_1 \left(\dfrac{p_2 T_2 - p_2 T_1}{\lambda} \right) = \dfrac{p_2 T_1 (T_2 - T_1)}{\lambda}

Substituting this back into the equation for ΔQ\Delta Q:
ΔQ=\Delta Q =\dfrac{3 p_1 V}{4 T_1} \times \dfrac{p_2 T_1 (T_2 - T_1)}{\lambda} = \dfrac{3 p_1 p_2 (T_2 - T_1) V}{4 \lambda}

Answer: \dfrac{3 p_1 p_2 (T_2 - T_1) V}{4 \lambda}
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