Quantrex Quantrex AcademyJEE · NEET · NDA PYQs with solutions Open app
Concepts Of Physics MCQ Edition [Volume 2]
Exam
Concepts Of Physics MCQ Edition [Volume 2]
Subject
Physics
Chapter
Laws of Thermodynamics

Concepts Of Physics MCQ Edition [Volume 2] · Physics · Laws of Thermodynamics

An adiabatic vessel of total volume V is partitioned into two equal...

An adiabatic vessel of total volume VV is partitioned into two equal parts by a fixed, conducting separator. The left part holds one mole of an ideal gas (U=1.5nRTU = 1.5 nRT) and the right part contains two moles of the same gas. Initially, the pressure on each side is pp. The system is allowed to rest for sufficient time until a steady state is achieved. Determine the increase in the internal energy of the gas in the left part.

Options

  1. ApV4\dfrac{pV}{4}
  2. B−pV2-\dfrac{pV}{2}
  3. C00
  4. D−pV4-\dfrac{pV}{4}

Correct answer

D. −pV4-\dfrac{pV}{4}

Step-by-step solution

Let the initial volume of each part be V2\dfrac{V}{2}.

The initial internal energy of a gas is given by U=1.5nRT=1.5pVpartU = 1.5 nRT = 1.5 pV_{part}.

For the left part:
UL,i=1.5p(V2)=3pV4U_{L,i} = 1.5 p \left(\dfrac{V}{2}\right) = \dfrac{3pV}{4}

For the right part:
UR,i=1.5p(V2)=3pV4U_{R,i} = 1.5 p \left(\dfrac{V}{2}\right) = \dfrac{3pV}{4}

Total initial internal energy of the system:
Ui=UL,i+UR,i=3pV4+3pV4=3pV2U_{i} = U_{L,i} + U_{R,i} = \dfrac{3pV}{4} + \dfrac{3pV}{4} = \dfrac{3pV}{2}

Since the vessel is adiabatic and the separator is fixed, the total internal energy of the system remains conserved. The conducting separator allows heat exchange until a common final temperature TfT_f is reached.

Total final internal energy:
Uf=1.5(nL+nR)RTf=1.5(1+2)RTf=4.5RTfU_{f} = 1.5 (n_L + n_R) R T_f = 1.5 (1 + 2) R T_f = 4.5 R T_f

Equating initial and final internal energies:
4.5RTf=3pV2⇒RTf=pV34.5 R T_f = \dfrac{3pV}{2} \Rightarrow R T_f = \dfrac{pV}{3}

The final internal energy of the left part is:
UL,f=1.5nLRTf=1.5(1)(pV3)=pV2U_{L,f} = 1.5 n_L R T_f = 1.5 (1) \left(\dfrac{pV}{3}\right) = \dfrac{pV}{2}

The increase in the internal energy of the gas in the left part is:
ΔUL=UL,f−UL,i=pV2−3pV4=−pV4\Delta U_L = U_{L,f} - U_{L,i} = \dfrac{pV}{2} - \dfrac{3pV}{4} = -\dfrac{pV}{4}
Practice Laws of Thermodynamics on Quantrex Academy →

More from Laws of Thermodynamics

A paddle wheel is coupled to a mass of 12 kg via fixed frictionless pulleys. The paddle… Concepts Of Physics MCQ Edition [Volume 2]A 100 kg block is started with a speed of 2.0 m s^ -1 on a long, rough belt maintained in… Concepts Of Physics MCQ Edition [Volume 2]Water at 15^ ^ ^ ∘ C is contained inside a closed, thermally insulated copper vessel. The… Concepts Of Physics MCQ Edition [Volume 2]Water at 15^ ^ ^ ∘ C is contained inside a closed, thermally insulated copper vessel. The… Concepts Of Physics MCQ Edition [Volume 2]A 100 kg block is started with a speed of 2.0 m s^ -1 on a long, rough belt fixed in a… Concepts Of Physics MCQ Edition [Volume 2]A gas undergoes a process where its pressure varies linearly with volume from 10 kPa… Concepts Of Physics MCQ Edition [Volume 2]Determine the change in the internal energy of a gas confined in a rigid container when… Concepts Of Physics MCQ Edition [Volume 2]An ideal gas is taken from an initial state i to a final state f such that the ratio of… Concepts Of Physics MCQ Edition [Volume 2] Full Laws of Thermodynamics list All Concepts Of Physics MCQ Edition [Volume 2] PYQs