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Concepts Of Physics MCQ Edition [Volume 2]
Exam
Concepts Of Physics MCQ Edition [Volume 2]
Subject
Physics
Chapter
Thermal and Chemical Effects of Electric Current

Concepts Of Physics MCQ Edition [Volume 2] · Physics · Thermal and Chemical Effects of Electric Current

A brass plate with a surface area of 200 cm^2 on one side is...

A brass plate with a surface area of 200 cm2200 \text{ cm}^2 on one side is electroplated with 0.10 mm0.10 \text{ mm} thick silver layers on both sides using a 15 A15 \text{ A} current. Determine the time taken to complete the job. The specific gravity of silver is 10.510.5 and its atomic weight is 107.9 g mol−1107.9 \text{ g mol}^{-1}.

Options

  1. A84 minutes84 \text{ minutes}
  2. B63 minutes63 \text{ minutes}
  3. C21 minutes21 \text{ minutes}
  4. D42 minutes42 \text{ minutes}

Correct answer

D. 42 minutes42 \text{ minutes}

Step-by-step solution

Total surface area to be electroplated (both sides) =2×200=400 cm2= 2 \times 200 = 400 \text{ cm}^2

Thickness of the silver layer =0.10 mm=0.01 cm= 0.10 \text{ mm} = 0.01 \text{ cm}

Volume of silver deposited =Area×Thickness=400×0.01=4 cm3= \text{Area} \times \text{Thickness} = 400 \times 0.01 = 4 \text{ cm}^3

Mass of silver deposited, m=Volume×Density=4×10.5=42 gm = \text{Volume} \times \text{Density} = 4 \times 10.5 = 42 \text{ g}

According to Faraday's first law of electrolysis:

m=MnFItm = \dfrac{M}{nF} I t

For silver, the valency n=1n = 1. Substituting the given values:

42=107.91×96500×15×t42 = \dfrac{107.9}{1 \times 96500} \times 15 \times t

t=42×96500107.9×15 st = \dfrac{42 \times 96500}{107.9 \times 15} \text{ s}

Converting the time into minutes:

t=42×96500107.9×15×60 mint = \dfrac{42 \times 96500}{107.9 \times 15 \times 60} \text{ min}

t=405300097110 min≈41.73 mint = \dfrac{4053000}{97110} \text{ min} \approx 41.73 \text{ min}

Rounding off to the nearest integer, the time taken is approximately 42 minutes42 \text{ minutes}.
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