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JEE Main 202310 AprilMorning Shift
Exam
JEE Main
Year
2023
Date
10 April
Shift
Morning Shift
Subject
Chemistry
Chapter
Hydrogen

JEE Main 2023 · 10 April · Morning Shift · Chemistry · Hydrogen

Given below are two reactions, involved in the commercial...

Given below are two reactions, involved in the commercial production of dihydrogen (H2)\left({H}_{2}\right). The two reactions are carried out at temperature “T1{T}_{1}” and “T2{T}_{2}”, respectively

C(s)+H2O(g)⟶T1CO(g)+H2(g)C\left(s\right) + {H}_{2}O\left(g\right)\overset{{T}_{1}}{⟶}CO\left(g\right) + {H}_{2}\left(g\right)

CO(g)+H2O(g)T2CatalystCO2(g)+H2(g)CO\left(g\right) + {H}_{2}O\left(g\right)\dfrac{{T}_{2}}{Catalyst}{CO}_{2}\left(g\right) + {H}_{2}\left(g\right)

The temperatures T1{T}_{1} and T2{T}_{2} are correctly related as

Options

  1. AT1=T2{T}_{1} = {T}_{2}
  2. BT1<T2{T}_{1} < {T}_{2}
  3. CT1=100K,T2=1270K{T}_{1} = 100K, {T}_{2} = 1270K
  4. DT1>T2{T}_{1} > {T}_{2}

Correct answer

D. T1>T2{T}_{1} > {T}_{2}

Step-by-step solution

CC\left(s\right) + {H}_{2}O(g)⟶1270K(T1)CO(g)+H2(g)\left(g\right)\overset{1270K\left({T}_{1}\right)}{⟶}CO\left(g\right) + {H}_{2}\left(g\right) is known as coal gasification reaction. The mixture produced in this reaction is called water gas.

CO(g)+H2O(g)673K(T2)Catalyst→CO2(g)+H2(g)CO\left(g\right) + {H}_{2}O\left(g\right)\dfrac{673K\left({T}_{2}\right)}{Catalyst} \to {CO}_{2}\left(g\right) + {H}_{2}\left(g\right) is known as water gas shift reaction. Using water gas shift reaction we can increase the concentration of hydrogen gas.

Hence, T1>T2{T}_{1} > {T}_{2}

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