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Concepts Of Physics MCQ Edition [Volume 2]
Exam
Concepts Of Physics MCQ Edition [Volume 2]
Subject
Physics
Chapter
Specific Heat Capacities of Gases

Concepts Of Physics MCQ Edition [Volume 2] · Physics · Specific Heat Capacities of Gases

For a certain gas sample, the quantity C_p - C_V is 1.00 R in state...

For a certain gas sample, the quantity Cp−CVC_p - C_V is 1.00R1.00 R in state AA and 1.08R1.08 R in state BB. If the pressures are denoted by pAp_A and pBp_B, and the temperatures by TAT_A and TBT_B for states AA and BB respectively, which of the following is most probable?

Options

  1. ApA>pBp_A > p_B and TA<TBT_A < T_B
  2. BpA=pBp_A = p_B and TA<TBT_A < T_B
  3. CpA<pBp_A < p_B and TA>TBT_A > T_B
  4. DpA>pBp_A > p_B and TA=TBT_A = T_B

Correct answer

C. pA<pBp_A < p_B and TA>TBT_A > T_B

Step-by-step solution

For an ideal gas, the difference between molar heat capacities is given by Mayer's relation Cp−CV=RC_p - C_V = R.

In state AA, Cp−CV=1.00RC_p - C_V = 1.00 R, which indicates that the gas behaves ideally.

In state BB, Cp−CV=1.08RC_p - C_V = 1.08 R, which indicates that the gas deviates from ideal behavior.

A real gas approaches ideal behavior at low pressures and high temperatures, while it deviates from ideal behavior at high pressures and low temperatures.

Therefore, state AA must correspond to a lower pressure and higher temperature compared to state BB.

This implies pA<pBp_A < p_B and TA>TBT_A > T_B.
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