Quantrex Quantrex AcademyJEE · NEET · NDA PYQs with solutions Open app
JEE Main 202324 JanuaryMorning Shift
Exam
JEE Main
Year
2023
Date
24 January
Shift
Morning Shift
Subject
Chemistry
Chapter
Ionic Equilibrium

JEE Main 2023 · 24 January · Morning Shift · Chemistry · Ionic Equilibrium

The dissociation constant of acetic is x × 10 ^ – 5 . When 25mLof0...

The dissociation constant of acetic is x×10–5x \times {10}^{– 5}. When 25mLof0.2MCH3COONa25mLof0 . 2M{CH}_{3}COONa solution is mixed with 25mLof0.02MCH3COOH25mLof0 . 02M{CH}_{3}COOH solution, the pHpH of the resultant solution is found to be equal to 55. The value of xx is _______.

Correct answer

0

Step-by-step solution

The Henderson equation for the given acidic buffer can be written as

pH=pKa+log[salt][weakacid]pH = pKa + log\dfrac{\left[salt\right]}{\left[weakacid\right]}

5=pKa+log25×0.225×0.02⇒pKa=4⇒Ka=10−4=10×10−55 = pKa + log\dfrac{25 \times 0 . 2}{25 \times 0 . 02} ⇒ pKa = 4 ⇒ Ka = {10}^{- 4} = 10 \times {10}^{- 5}

Hence, the value of xxis 1010.

Practice Ionic Equilibrium on Quantrex Academy →

More from Ionic Equilibrium

Given is a concentrated solution of a weak electrolyte A_xB_y of concentration 'c' and… JEE Main 2026M_3 A_2 is a sparingly soluble salt of molar mass y g mol ^ -1 and solubility x g L ^ -1… JEE Main 2026Arrange the following resultant mixtures in increasing order of their pH values A. 10 mL… JEE Main 202620 mL of a solution of acetic acid required 28.4 mL of 0.1 M NaOH for its neutralization.… JEE Main 2026The pH of a solution obtained by mixing 5 mL of 0.1 M NH_4OH solution with 250 mL of 0.1… JEE Main 2026The first and second ionization constants of a weak dibasic acid H_2 A are 8.1 × 10^ -8… JEE Main 2026At 25°C , 20.0 mL of 0.2 M weak monoprotic acid HX is titrated against 0.2 M NaOH. The pH… JEE Main 2026The solubility product constants of Ag_2CrO_4 and AgBr are 32x and 4y respectively at 298… JEE Main 2026 Full Ionic Equilibrium list All JEE Main PYQs